Lignin-based phenolic resin modified with whisker silicon and its ap-plication

Na Zhang; Zhuo Li; Yanan Xiao; Zheng Pan; Puyou Jia; Guodong Feng; Caiying Bao; Yonghong Zhou; Lilong Hua

doi:10.1016/j.jobab.2020.03.008

Volume 5 Issue 1

Feb. 2020

Turn off MathJax

Article Contents

Article Navigation > Journal of Bioresources and Bioproducts > 2020 > 5(1): 67-77

Na Zhang, Zhuo Li, Yanan Xiao, Zheng Pan, Puyou Jia, Guodong Feng, Caiying Bao, Yonghong Zhou, Lilong Hua. Lignin-based phenolic resin modified with whisker silicon and its ap-plication[J]. Journal of Bioresources and Bioproducts, 2020, 5(1): 67-77. doi: 10.1016/j.jobab.2020.03.008

Citation:

Na Zhang, Zhuo Li, Yanan Xiao, Zheng Pan, Puyou Jia, Guodong Feng, Caiying Bao, Yonghong Zhou, Lilong Hua. Lignin-based phenolic resin modified with whisker silicon and its ap-plication[J]. Journal of Bioresources and Bioproducts, 2020, 5(1): 67-77. doi: 10.1016/j.jobab.2020.03.008

Citation:

Na Zhang, Zhuo Li, Yanan Xiao, Zheng Pan, Puyou Jia, Guodong Feng, Caiying Bao, Yonghong Zhou, Lilong Hua. Lignin-based phenolic resin modified with whisker silicon and its ap-plication[J]. Journal of Bioresources and Bioproducts, 2020, 5(1): 67-77. doi: 10.1016/j.jobab.2020.03.008

PDF( 1890 KB)

Lignin-based phenolic resin modified with whisker silicon and its ap-plication

doi: 10.1016/j.jobab.2020.03.008

a.
Institute of Chemical Industry of Forest Products, Chinese Academy of Forest; Co-innovation Center of Efficient Processing and Utilization of Forest Resource, Nanjing Forestry University, Nanjing 210042, China
b.
School of Petrochemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, China

Funds:

Key R & D Plan of the 13th Five-Year Plan 2017YFD0601003

Key projects funded by the Chinese Academy of Forest 2017YFD0601003

Innovation Project of Institute of Forestry and Chemical Industry LHSXKQ11

More Information

Corresponding author: E-mail address: zhlh990907@sina.com (L. Hua)
Received Date: 2019-07-10
Accepted Date: 2019-09-20
Publish Date: 2020-01-01

Abstract

Abstract

In this study, lignin-based phenolic resin was modified with whisker silicon and preparation of the phenolic foam is carried out. The resin and foam materials were characterized by Fourier transform infrared spectroscopy (FT-IR), thermo gravimetric analyzer (TGA), thermal conductivity test, limit oxygen index (LOI) analyzer and cone calorimeter. The results showed that if the content of lignin and whisker silicon increases, the oxygen index of the foam increases and the calorific value of combustion decreases. However, if the amount of lignin increased, the open porosity of the foam and the thermal conductivity increased. When the lignin substitution rate was 30% and the whisker silicon addition amount was 1%, the phenolic foam (PF4) has the best performance:the 57.1% mass lost at 600℃ and the thermal stability was 16.8% higher than that of ordinary resin. The LOI was 49.6%, and 39.3% higher than that of ordinary phenolic foam.
- phenolic foam,
- phenolic resin,
- lignin,
- whisker silicon

FullText(HTML)

References(20)

References

Arafa, I.M., Fares, M.M., Barham, A.S., 2004. Sol-gel preparation and properties of interpenetrating, encapsulating and blend silica-based urea-formaldehyde hybrid composite materials. Eur. Polym. J. 40, 1477-1487. doi: 10.1016/j.eurpolymj.2004.02.014

Guo, Y.J., Hu, L.H., Zhang, N., 2017. Characterization of thermal stability and toughness of nanoSiO₂-lignin based phenolic foam. Chem. Ind. Eng. Prog. 36, 4569-4574. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hgjz201712033

Hakkı Alma, M., Kelley, S., 2000. Thermal stability of novolak-type thermosettings made by the condensation of bark and phenol. Polym. Degrad. Stab. 68, 413-418. doi: 10.1016/S0141-3910(00)00029-X

Haraguchi, K., Usami, Y., Ono, Y, 1998. The preparation and characterization of hybrid materials composed of phenolic resin and silica. Journal of Materials Science 33, 3337-3344. doi: 10.1023/A:1013237430504

Hu, L.H., Zhou, Y.H., Liu, R.J., Zhang, M, 2012. Progress of bio-based phenolic foam. New Chem. Mater. 40, 44-46. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hgxxcl201201014

Hu, L.H., Zhou, Y.H., Liu, R.J., Zhang, M., Yang, X.H, 2013. Synthesis of foaming resol resin modified with oxidatively degraded lignosulfonate. Ind. Crop. Prod. 44, 364-366. doi: 10.1016/j.indcrop.2012.11.034

Li, X.F., Luo, X.G., 2004. Advances of the application of lignin applied in plastics. China Pulp Pap. Ind. 6, 54-57. http://cn.bing.com/academic/profile?id=721cf28e96de15e95f7d38fe90724537&encoded=0&v=paper_preview&mkt=zh-cn

Liang, B.C., Li, X.Y., Hu, L.H., Bo, C.Y., Zhou, J., Zhou, Y.H, 2016. Foaming resol resin modified with polyhydroxylated cardanol and its application to phenolic foams. Ind. Crop. Prod. 80, 194-196. doi: 10.1016/j.indcrop.2015.11.087

Lin, R.H., Xi, Y.X., Shao, Y.X., 2004. Phenolic resin modified by nano-copper and its applied behaviors. Acta Mater. Compos. Sin. 21, 114-118. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=fhclxb200406020

Liu, G., Qiu, X., Yang, D., 2008. Properties of wheat straw soda lignin of different molecular weights and its influence on properties of LPF adhesive. J. Chem. Ind. Eng. (China) 59, 1590.

Liu, J.H., Zhao, B.H., Li, J.Z., Liu, X., Li, D.F., 2013. Mechanical property and thermostability of phenolic foams modiifed by tannins. Eng. Plast. Appl. 7, 13-16. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=gcslyy201307006

Liu, Y.H., Jing, X.L., 2007. Pyrolysis and structure of hyperbranched polyborate modified phenolic resins. Carbon 45, 1965-1971. doi: 10.1016/j.carbon.2007.06.008

Luo, J.H., Tang, Z.G., 2005. Progress in research on technology for blending lignin with plastic. China Synth. Resin Plast. 22, 81-84. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hcszjsl200504020

Tang, L.L., Li, N.N., Wu, P.X., 2008. High Performance Phenolic Resin and Its Application Technology. Beijing: Chemical Industry Press, 2-3.

Wang, J.G., Jiang, H.Y., Jiang, N., 2009a. Study on the pyrolysis of phenol-formaldehyde (PF) resin and modified PF resin. Thermochimica Acta 496, 136-142. doi: 10.1016/j.tca.2009.07.012

Wang, M.C., Leitch, M., (Charles) Xu, C., 2009b. Synthesis of phenol-formaldehyde resol resins using organosolv pine lignins. Eur. Polym. J. 45, 3380-3388. doi: 10.1016/j.eurpolymj.2009.10.003

Wei, H.C., Li, Y., Gao, C.M., 2006. Effect of carbon nanotubes on mechanical properties of phenolic resin/carbon fiber composites. Eng. Plast. Appl. 34, 13-15.

Yuan, B., Zheng, C., Lu, H., 2012. Research and application of phenolic resin in exterior wall insulation and fire prevention. Eng. Plast. Appl. 40, 28-30.

Zhang, X.Q., Looney, M.G., Solomon, D.H., Whittaker, A.K, 1997. The chemistry of novolac resins:3. ¹³C and 15N n.m.r. studies of curing with hexamethylenetetramine. Polymer 38, 5835-5848. http://d.old.wanfangdata.com.cn/OAPaper/oai_doaj-articles_dd448dbe9fd9b63d870c6e0be951a805

Zhong, Y., Ji, Y.X., Zhu, D.K., 2010. Preparation of flexible phenolic foam plastics. Mod. Chem. Ind. 30, 60-62. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=10.1177/0021955X7300900106

Relative Articles

Supplements(0)

Cited By

Proportional views