Multifunctional Polypyrrole-silver Coated Layered Double Hydroxides Embedded into a Biodegradable Polymer Matrix for Enhanced Antibacterial and Gas Barrier Properties

Haibo HUANG; Long MAO; Zhihan LI; Yuejun LIU; Shuhong FAN; Yao JIN; Jianda XIE

doi:10.12162/jbb.v4i4.015

Volume 4 Issue 4

Nov. 2019

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Article Navigation > Journal of Bioresources and Bioproducts > 2019 > 4(4): 231-241

Haibo HUANG, Long MAO, Zhihan LI, Yuejun LIU, Shuhong FAN, Yao JIN, Jianda XIE. Multifunctional Polypyrrole-silver Coated Layered Double Hydroxides Embedded into a Biodegradable Polymer Matrix for Enhanced Antibacterial and Gas Barrier Properties[J]. Journal of Bioresources and Bioproducts, 2019, 4(4): 231-241. doi: 10.12162/jbb.v4i4.015

Citation:

Haibo HUANG, Long MAO, Zhihan LI, Yuejun LIU, Shuhong FAN, Yao JIN, Jianda XIE. Multifunctional Polypyrrole-silver Coated Layered Double Hydroxides Embedded into a Biodegradable Polymer Matrix for Enhanced Antibacterial and Gas Barrier Properties[J]. Journal of Bioresources and Bioproducts, 2019, 4(4): 231-241. doi: 10.12162/jbb.v4i4.015

Citation:

Haibo HUANG, Long MAO, Zhihan LI, Yuejun LIU, Shuhong FAN, Yao JIN, Jianda XIE. Multifunctional Polypyrrole-silver Coated Layered Double Hydroxides Embedded into a Biodegradable Polymer Matrix for Enhanced Antibacterial and Gas Barrier Properties[J]. Journal of Bioresources and Bioproducts, 2019, 4(4): 231-241. doi: 10.12162/jbb.v4i4.015

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Multifunctional Polypyrrole-silver Coated Layered Double Hydroxides Embedded into a Biodegradable Polymer Matrix for Enhanced Antibacterial and Gas Barrier Properties

doi: 10.12162/jbb.v4i4.015

Haibo HUANG¹,
Long MAO^{1, 2
,
,},
Zhihan LI¹,
Yuejun LIU^{1, 2
,
,},
Shuhong FAN¹,
Yao JIN¹,
Jianda XIE²

1.
Key Laboratory of Advanced Packaging Materials and Technology of Hunan Province, Hunan University of Technology, Zhuzhou 412007, China
2.
Fujian Provincial Key Laboratory of Functional Materials and Applications, Xiamen University of Technology, Xiamen 361024, China

More Information

Corresponding author: Long MAO, E-mail:maolong0412@163.com; Yuejun LIU, E-mail:yjliu_2005@126.com
Received Date: 2019-06-21
Accepted Date: 2019-08-10
Publish Date: 2019-10-01

Abstract

Abstract

In this study, polypyrrole-silver coated layered double hydroxides (LDHs@PPy-Ag) was prepared by chemical polymerization of pyrrole (Py) with silver ions. Silver nanoparticles (AgNPs) could be uniformly reduced onto PPy coatings in situ by redox reaction during simultaneous polymerization process. And LDHs@PPy-Ag/poly(ε-caprolactone) (PCL) nanocomposites were fabricated by solution casting method. It is revealed that spherical AgNPs are loaded on PPy coatings uniformly. Particularly, compared with pure PCL, LDHs@PPy-Ag/PCL nanocomposites with incorporation of only 1 wt% LDHs@PPy-Ag show a 17% increase in tensile strength (36.5 MPa) and a 29% increase in elongation at break (822%). Upon PPy-Ag coatings onto original LDHs, relative permeability of LDHs@PPy-Ag/PCL nanocomposites decreases to 52% with the same addition. Meanwhile, due to the double antibacterial activity of PPy and AgNPs, the antibacterial rate of LDHs@PPy-Ag reaches 100%. And the corresponding LDHs@PPy-Ag/PCL nanocomposites also show outstanding antibacterial activity. Considering the superiority of their comprehensive performance, antibacterial LDHs@PPy-Ag/PCL nanocomposites can be used further for the application as biodegradable polymeric active packaging materials.
- antibacterial activity,
- layered double hydroxides,
- polypyrrole,
- silver,
- gas barrier properties

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References(43)

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