Volume 5 Issue 1
Feb.  2020
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Xiaoya Jiang, Yuanyuan Bai, Xuefeng Chen, Wen Liu. A review on raw materials, commercial production and properties of lyocell fiber[J]. Journal of Bioresources and Bioproducts, 2020, 5(1): 16-25. doi: 10.1016/j.jobab.2020.03.002
Citation: Xiaoya Jiang, Yuanyuan Bai, Xuefeng Chen, Wen Liu. A review on raw materials, commercial production and properties of lyocell fiber[J]. Journal of Bioresources and Bioproducts, 2020, 5(1): 16-25. doi: 10.1016/j.jobab.2020.03.002

A review on raw materials, commercial production and properties of lyocell fiber

doi: 10.1016/j.jobab.2020.03.002
Funds:

National Key Research and Development Program of China 2017YFB0308200

National Key Research and Development Program of China 2017YFE0101500

More Information
  • Corresponding author: Xiaoya Jiang, E-mail addresses:xiaoya_jiang0794@163.com
  • Received Date: 2019-08-30
  • Accepted Date: 2019-10-29
  • Publish Date: 2020-01-01
  • As one of the regenerated cellulosic fibers,viscose fiber has the largest output. However,the wastes produced in the manufacturing process are difficult to eliminate,which restricts the development of viscose fiber. Lyocell fiber is claimed as "green and eco-friendly fiber" with a good application prospect in the 21st century. The preparation of lyocell fiber is based on the cellulosic non-derivative solution system,i.e.,N-methylmorpholine-N-oxide system which is nontoxic and recyclable. Firstly,the demands of dissolving pulp properties for regenerated-cellulosic fiber (RCF),especially for lyocell fiber,were introduced in detail. Next,the whole manufacturing processes including pretreatment,preparation of spinning dope,spinning,posttreatment and efficient solvent recovery technologies were reviewed emphatically. Then,the properties and structural characteristics of lyocell fiber were illustrated. At last,some suggestions were proposed for lyocell fiber development in China.

     

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  • Abu-Rous, M., Varga, K., Bechtold, T., Schuster, K.C., 2007. A new method to visualize and characterize the pore structure of TENCEL® (Lyocell) and other man-made cellulosic fibres using a fluorescent dye molecular probe. J. Appl. Polym. Sci. 106, 2083-2091. doi: 10.1002/app.26722
    Andre, P., Marsh, K.N., Pang, S., 2010. Reflections on the solubility of cellulose. Ind. Eng. Chem. Res. 49, 11121-11130. doi: 10.1021/ie1006596
    Biganska, O., Navard, P., 2009. Morphology of cellulose objects regenerated from cellulose-N-methylmorpholine N-oxide-water solutions. Cellulose 16, 179-188. doi: 10.1007/s10570-008-9256-y
    Camper, I.P., Bott, C.B., 2006. Improvement of an industrial wastewater treatment system at a former viscose rayon plant-results from two-stage biological leachate treatability testing. Proc. Water Environ. Fed. 2006, 1830-1845. doi: 10.2175/193864706783750394
    Chaudemanche, C., Navard, P., 2011. Swelling and dissolution mechanisms of regenerated Lyocell cellulose fibers. Cellulose 18, 1-15. doi: 10.1007/s10570-010-9460-4
    Chavan, R., Patra, A., 2004. Development and processing of lyocell. Indian Journal of Fibre and Textile Research 29, 483. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=Open J-Gate000000686675
    Chen, C. X., Liu, Y. S., Duan, C., 2015. Comparison of production technology and characteristics of the dissolving pulps based on AS and PHK processes. China Pulp & Paper 34, 66-70. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgzz201512014
    Chen, H.L., Burns, L.D., 2006. Environmental analysis of textile products. Cloth. Text. Res. J. 24, 248-261. doi: 10.1177/0887302X06293065
    Cheng, B. W., 1999. Status and development of fiber. Artificial Fiber 2, 26-30. http://d.old.wanfangdata.com.cn/Periodical/cyyfzp201805001
    Deo, H. T., 2001. Eco friendly textile production. Indian Journal of Fibre & Textile Research 26, 61-73. http://d.old.wanfangdata.com.cn/NSTLQK/NSTL_QKJJ0211767461/
    Dogan, H., Hilmioglu, N.D., 2009. Dissolution of cellulose with NMMO by microwave heating. Carbohydr. Polym. 75, 90-94. doi: 10.1016/j.carbpol.2008.06.014
    Duan, J. L., Hu, X. C., Zhang, T. L., Shao, H. L., 1999. Influence of the coagulation bath concentration on the mechanical properties and the maximum spinning speed of lyocell fiber. Synthetic Fiber, 28, 5-8. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199900256065
    Duan, J. L., Shao, H. L., Zhang, T. L., Hu, X. C., 2001. Influence of the coagulation bath temperature on the structure and properties of lyocell fiber. Journal of textile research 22, 13-15.
    Ertas, Y., Uyar, T, 2017. Fabrication of cellulose acetate/polybenzoxazine cross-linked electrospun nanofibrous membrane for water treatment. Carbohydr. Polym. 177, 378-387. doi: 10.1016/j.carbpol.2017.08.127
    Eva, B., 2008. Lyocell, the new generation of regenerated cellulose. Acta Polytechnica Hungarica 5, 11-18. http://d.old.wanfangdata.com.cn/OAPaper/oai_doaj-articles_db1b4dcd727e2e23eab8e2a8c0b27bef
    Fink, H., Weigel, P., Purz, H., Ganster, J., 2001. Structure formation of regenerated cellulose materials from NMMO-solutions. Prog. Polym. Sci. 26, 1473-1524. doi: 10.1016/S0079-6700(01)00025-9
    Fu, F.Y., Yang, Q.L., Zhou, J.P., Hu, H.Z., Jia, B.Q., Zhang, L.N., 2014. Structure and properties of regenerated cellulose filaments prepared from cellulose carbamate-NaOH/ZnO aqueous solution. ACS Sustainable Chem. Eng. 2, 2604-2612. doi: 10.1021/sc500559g
    Gao, D. C., Lu, X. Y., Wang, H. P., 2019a. Technological development of industrial process of lyocell fiber. Artificial Fiber 49, 2-16.
    Gao, D. C., Lu, X. Y., Wang, H. P., 2019b. Technological development of industrial process of lyocell fiber. Artificial Fiber 49, 13-19.
    Gavillon, R., Budtova, T., 2007. Kinetics of cellulose regeneration from cellulose-NaOH-water gels and comparison with cellu-lose-N-methylmorpholine-N-oxide-water solutions. Biomacromolecules 8, 424-432. doi: 10.1021/bm060376q
    Hohberg, T., Thumm, S., 1998. Finishing of lyocell. Melliand 4, 59-67. http://d.old.wanfangdata.com.cn/Periodical/fzxb202002014
    Ingildeev, D., Effenberger, F., Bredereck, K., Hermanutz, F., 2013. Comparison of direct solvents for regenerated cellulosic fibers via the lyocell process and by means of ionic liquids. J. Appl. Polym. Sci. 128, 4141-4150. doi: 10.1002/app.38470
    Ingruber, O. V., Kocurek, M. J., Wong, A., 1985. Sulfite science and technology. Beijing: Joint Textbook Committee of the Paper Industry.
    Kang, Y., Chai, X. J., Ai, G., 2011. Properties and application of copper ammonia fiber. Hebei Textile 1, 10-12.
    Karimi, K., Taherzadeh, M.J., 2016. A critical review of analytical methods in pretreatment of lignocelluloses:Composition, imaging, and crystallinity. Bioresour. Technol. 200, 1008-1018. doi: 10.1016/j.biortech.2015.11.022
    Kongdee, A., Bechtold, T., Burtscher, E., Scheinecker, M., 2004. The influence of wet/dry treatment on pore structure-the correlation of pore parameters, water retention and moisture regain values. Carbohydr. Polym. 57, 39-44. doi: 10.1016/j.carbpol.2004.03.025
    Konkin, A., Wendler, F., Meister, F., Roth, H.K., Aganov, A., Ambacher, O., 2007. Degradation processes in the cellu-lose/N-methylmorpholine-N-oxide system studied by HPLC and ESR. Radical formation/recombination kinetics under UV photolysis at 77 K. Cellulose 14, 457-468.
    Kotek, R., 2008. Recent advances in polymer fibers. Polym. Rev. 48, 221-229. doi: 10.1080/15583720802020038
    LaNieve, H., 2006. Cellulose acetate and triacetate fibers. (3rd ed.). U.S.: CRC Press, 774-808.
    Li, J., 2018. Patent analysis on lyocell fiber of Lenzing Group. Advanced Material Industry 295, 42-45.
    Li, J.G., Zhang, H.J., Duan, C., Liu, Y.S., Ni, Y.H., 2015. Enhancing hemicelluloses removal from a softwood sulfite pulp. Bioresour. Technol. 192, 11-16. doi: 10.1016/j.biortech.2015.04.107
    Li, Q. C., Huang, Z. Q., 2001. Preliminary study on the dissolving pulp for lyocell fiber. Guangxi Chemical fiber Communication 1, 5-8.
    Lin, Z. W., Ke, J. J., 2000. History, technology, properties and development of lyocell fiber. Textile Science Research 1, 29-33.
    Liu, R. G., 1997. New special of cellulosic fiber:lyocell. Textile Technology Overseas 9, 25-28.
    Liu, Y.S., Chen, C.X., Li, J.G., Duan, C., Zheng, L.Q., Ni, Y.H, 2016. Quality requirements and production technologies of dissolving pulp. China Pulp Pap. 35, 56-61. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgzz201602011
    Luo, X.G., Liu, S.L., Zhou, J.P., Zhang, L.N., 2009. In situ synthesis of Fe3O4/cellulose microspheres with magnetic-induced protein delivery. J. Mater. Chem. 19, 3538.
    Maréchal, A., 1993. Acid extraction of the alkaline wood pulps (kraft or SODA/AQ) before or during bleaching reason and opportunity. J. Wood Chem. Technol. 13, 261-281. doi: 10.1080/02773819308020517
    Maron, R., Michels, C., Taeger, E., 1994. Investigations for preparation of cellulose solutions in NMMO and the following forming. Lenzinger Berichte 74, 27-29.
    Medronho, B., Lindman, B., 2014. Competing forces during cellulose dissolution:From solvents to mechanisms. Curr. Opin. Colloid Interface Sci. 19, 32-40. doi: 10.1016/j.cocis.2013.12.001
    Meiste, R. G., Wechsle, R. M., 1998. Biodegradation of N-methylmorpholine-N-oxide. Biodegradation 9, 91-102. doi: 10.1023/A:1008264908921
    Mo, D. C., 2002. Review of spinning process of lyocell fiber. Guangxi Chemical fiber Communication 1, 25-29. (in Chinese)
    Mortimer, S. A., Peguy, A. A., 1996a. The formation of structure in the spinning and coagulation of lyocell fibers. Cellulose Chemistry and Technology 30, 71-82.
    Mortimer, S. A., Peguy, A. A., Ball, R. C., 1996. Influence of the physical process parameters on the structure formation of lyocell fibres. Cel-lulose Chemistry and Technology 30, 251-266. http://www.researchgate.net/publication/279901655_Influence_of_the_physical_process_parameters_on_the_structure_formation_of_lyocell_fibres
    Mortimer, S.A., Peguy, A.A., 1996b. The influence of air-gap conditions on the structure formation of Lyocell fibers. J. Appl. Polym. Sci. 60, 1747-1756. doi: 10.1002/(SICI)1097-4628(19960606)60:10<1747::AID-APP28>3.0.CO;2-#
    Peng, H.F., Dai, G.L., Wang, S.P., Xu, H.Y., 2017. The evolution behavior and dissolution mechanism of cellulose in aqueous solvent. J. Mol. Liq. 241, 959-966. doi: 10.1016/j.molliq.2017.06.103
    Peng, S. J., 2003. Studies on high strength lyocell fiber and Its application for the precursor of carbon fiber. Shanghai: Donghua University.
    Perepelkin, K.E., 2007. Lyocell fibres based on direct dissolution of cellulose in N-methylmorpholine N-oxide:Development and prospects. Fibre Chem. 39, 163-172. doi: 10.1007/s10692-007-0032-9
    Periyasamy, A. P., Khanum, M. R., 2012. Effect of fbrillation on pilling tendency of lyocell fiber. Bangladesh Textile Today 4, 31-37.
    Pinkert, A., Marsh, K.N., Pang, S.S., 2010. Reflections on the solubility of cellulose. Ind. Eng. Chem. Res. 49, 11121-11130. doi: 10.1021/ie1006596
    Qian, B. Z., 2018. Reduction in cost of Lyocell fiber must cross three barriers. Advances in fine petrochemicals 3, 49.
    Ramos, L. A., Morgado, D. L., Gessner, F., Frollini, E., Seoudb, O. A., 2011. A physical organic chemistry approach to dissolution of cellulose:effects of cellulose mercerization on its properties and on the kinetics of its decrystallization. Arkivoc Online Journal of Organic Chemistry 7, 416-425. http://cn.bing.com/academic/profile?id=9d54d414a000bd17d3a16dfa53d1b4bd&encoded=0&v=paper_preview&mkt=zh-cn
    Reddy, N., Yang, Y.Q., 2014. The N-methylmorpholine-N-oxide (NMMO) process of producing regenerated fibers. Innovative Biofibers from Renewable Resources. Berlin, Heidelberg: Springer Berlin Heidelberg, 65-71.
    Rohrer, C., Retzl, P., Firgo, H., 2001. Lyocell LF-Profile of a fibrillation-free fibre from Lenzing. Lenzinger Berichte 80, 75-79.
    Rosenau, T., Potthast, A., Sixta, H., Kosma, P., 2001. The chemistry of side reactions and byproduct formation in the system NMMO/cellulose (Lyocell process). Prog. Polym. Sci. 26, 1763-1837. doi: 10.1016/S0079-6700(01)00023-5
    Sayyed, A., Deshmukh, N.A., Pinjari, D.V., 2019. A critical review of manufacturing processes used in regenerated cellulosic fibres:viscose, cellulose acetate, cuprammonium, LiCl/DMAc, ionic liquids, and NMMO based lyocell. Cellulose 26, 2913-2940. doi: 10.1007/s10570-019-02318-y
    Sayyed, A.J., Mohite, L.V., Deshmukh, N.A., Pinjari, D.V., 2018. Structural characterization of cellulose pulp in aqueous NMMO solution under the process conditions of lyocell slurry. Carbohydr. Polym. 206, 220-228. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=9c6a6324b4dbd11bccb3a623747b7540
    Schild, G., Sixta, H., 2011. Sulfur-free dissolving pulps and their application for viscose and lyocell. Cellulose 18, 1113-1128. doi: 10.1007/s10570-011-9532-0
    Schuster, K.C., Rohrer, C., Eichinger, D., Schmidtbauer, J., Aldred, P., Firgo, H., Environmentally friendly lyocell fibers. Natural Fibers, Plastics and Composites. Boston, MA: Springer US, 2004: 123-146.
    Shaikh, T., Chaudhari, S., Varma, A., 2012. Viscose rayon:a legendary development in the manmade textile. International J. Eng. Res. Appl. 2, 675-680.
    Sixta, H., 2008. Introduction. Handbook of Pulp. Weinheim, Germany: Wiley-VCH Verlag GmbH, 2-19.
    Thomas, H., Rene, D., Andreas, K., 2000. Effective preparation of cellulose derivatives in a new simple cellulose solvent. Macromol. Chem. Phys. 201, 627-631. doi: 10.1002/(SICI)1521-3935(20000301)201:6<627::AID-MACP627>3.0.CO;2-Y
    Tong, M. W., Zhang, H. R., Shao, H. L., Hu, X. C., 2005. Structure and properties of lyocell fiber from high hemicellulose pulp. Synthetic Fiber 8, 1-4. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hcxw200508001
    Treiber, E., Rehnstrom, J., Ameen, C., 1962. A small scale laboratory viscose plant for testing rayon grade pulps. Das Papier 16, 85-94.
    Uddin, A.J., Yamamoto, A., Gotoh, Y., Nagura, M., Iwata, M., 2010. Preparation and physical properties of regenerated cellulose fibres from sugarcane bagasse. Text. Res. J. 80, 1846-1858. doi: 10.1177/0040517510369408
    Vanhoorne, M., van den Berge, L., Devreese, A., Tijtgat, E., van Poucke, L., van Peteghem, C. V., 1991. Survey of chemical exposures in a viscose rayon plant. Ann. Occup. Hyg. 35, 619-631. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=HighWire000005805971
    Vila, C., Santos, V., Parajó, J.C., 2004. Dissolving pulp from TCF bleached Acetosolv beech pulp. J. Chem. Technol. Biotechnol. 79, 1098-1104. doi: 10.1002/jctb.1090
    Viviana, K., 2010. Conversion of wood and non-wood paper-grade pulps to dissolving-grade pulps. Stockholm: Sweden Royal Institute of Technology.
    Wan, Y. B., Wang, S. Y., 1999. Fibrilation properties of solvated cellulosic fiber. Journal of Textile Research 20, 19-21.
    Wang, L. J., Liu, Y. N., Fang, D., Li, Z. J., 2017. Status and development research of Lyocell fiber at home and abroad. Journal of Textile Research 38, 164-170. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=fzxb201704029
    Wang, L. J., Pan, S. J., 2000. Discussion on the development prospect of lyocell fiber in China from its experiment and practice. Artificial Fiber 30, 26-31.
    Wang, S. L., 2010. Studies on the structure and properties of cellulose acetate fiber. Shandong: Qingdao University.
    Wang, S., Yang, Y.W., Lu, A., Zhang, L.N., 2019. Construction of cellulose/ZnO composite microspheres in NaOH/zinc nitrate aqueous solution via one-step method. Cellulose 26, 557-568. doi: 10.1007/s10570-018-2201-9
    Wang, Z. H., 2018. Research on cellulose acetate and its application. Acetaldehyde Acetic Acide Chemical Industry 5, 17-25.
    Wendler, F., Konkin, A., Heinze, T., 2008. Studies on the stabilization of modified lyocell solutions. Macromol. Symp. 262, 72-84. doi: 10.1002/masy.200850208
    White, P., 2001. Lyocell:the production process and market development. Regenerated Cellulose Fibres. 1, 62-87. http://d.old.wanfangdata.com.cn/Periodical/gfzclkxygc200505026
    Woodings, C., 2001. Regenerated cellulose fibres. Cambridge: Woodhead Publishing Limited.
    Xu, H., Xu, M. F., Cheng, C. Z., Li, Q., 2012. Influence of copper on the thermal stability of the lyocell fiber spinning solution. Synthetic Fiber in China 41, 13-16.
    Yang, M. H., Yang, D. J., 2002. Relationship between structure and properties of lyocell fiber. Journal of Chengdu Textile College 19, 10-12.
    Yuan, C.P., Shi, W.T., Chen, P., Chen, H.X., Zhang, L.H., Hu, G., Jin, L.M., Xie, H.B., Zheng, Q., Lu, S.J., 2019. Dissolution and transesterifi-cation of cellulose in γ-valerolactone promoted by ionic liquids. New J. Chem. 43, 330-337. doi: 10.1039/C8NJ03505A
    Yue, W. T., Zhou, M. H., Shao, H. L., Hu, X. C., 2002. Purification and regeneration of the aqueous solutions of NMMO using ion exchange resin. Synthetic Fiber 2, 28-35. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hcxw200202008
    Zhang, H. H., Wei, M. Y., Shao, H. L., 2010. Effect of cellulose pulp on the properties of lyocell fiber used as tire cord. Journal of Donghua University:Natural Science 5, 486-490. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgfzdxxb201005002
    Zhang, H. R., 2007. Study on lyocell fiber from a cheap pulp with high hemicellulose content. Shanghai: Donghua University.
    Zhang, J. C., 1999. Study on the structure and properties of lyocell fiber. Chengdu: Sichuan University.
    Zhang, S. K., Chen, C. X., Duan, C., Hu, H. C., Li, H. L., Li, J. G., Liu, Y. S., Ma, X. J., Jaroslav, S., Ni, Y. H., 2018. Regenerated cellulose by the lyocell process, a brief review of the process and properties. Bioresour. 13, 1-16.
    Zhang, S., 2010. Preparing regenerated cellulose fibers using novel solution and its structure and properties. Shanghai: Donghua University.
    Zhang, Y.P., Shao, H.L., Wu, C.X., Hu, X.C., 2001. Formation and characterization of cellulose membranes fromN-methylmorpholine-N-oxide solution. Macromol. Biosci. 1, 141-148. doi: 10.1002/1616-5195(20010601)1:4<141::AID-MABI141>3.0.CO;2-J
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