Packaging and degradability properties of polyvinyl alcohol/gelatin nanocomposite films filled water hyacinth cellulose nanocrystals

Henry C. Oyeoka; Chinomso M. Ewulonu; Iheoma C. Nwuzor; Chizoba M. Obele; Joseph T. Nwabanne

doi:10.1016/j.jobab.2021.02.009

Volume 6 Issue 2

Jun. 2021

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Article Navigation > Journal of Bioresources and Bioproducts > 2021 > 6(2): 168-185

Henry C. Oyeoka, Chinomso M. Ewulonu, Iheoma C. Nwuzor, Chizoba M. Obele, Joseph T. Nwabanne. Packaging and degradability properties of polyvinyl alcohol/gelatin nanocomposite films filled water hyacinth cellulose nanocrystals[J]. Journal of Bioresources and Bioproducts, 2021, 6(2): 168-185. doi: 10.1016/j.jobab.2021.02.009

Citation:

Henry C. Oyeoka, Chinomso M. Ewulonu, Iheoma C. Nwuzor, Chizoba M. Obele, Joseph T. Nwabanne. Packaging and degradability properties of polyvinyl alcohol/gelatin nanocomposite films filled water hyacinth cellulose nanocrystals[J]. Journal of Bioresources and Bioproducts, 2021, 6(2): 168-185. doi: 10.1016/j.jobab.2021.02.009

Citation:

Henry C. Oyeoka, Chinomso M. Ewulonu, Iheoma C. Nwuzor, Chizoba M. Obele, Joseph T. Nwabanne. Packaging and degradability properties of polyvinyl alcohol/gelatin nanocomposite films filled water hyacinth cellulose nanocrystals[J]. Journal of Bioresources and Bioproducts, 2021, 6(2): 168-185. doi: 10.1016/j.jobab.2021.02.009

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Packaging and degradability properties of polyvinyl alcohol/gelatin nanocomposite films filled water hyacinth cellulose nanocrystals

doi: 10.1016/j.jobab.2021.02.009

a.
Department of Polymer and Textile Engineering, Nnamdi Azikiwe University, P. M. B. 5025, Awka, Nigeria
b.
Department of Chemical Engineering, Nnamdi Azikiwe University, P. M. B. 5025, Awka, Nigeria
c.
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, 29 Zhongguancun East Road, Haidian District, Beijing 100190, China

More Information

Corresponding author: E-mail address: cm.ewulonu@unizik.edu.ng (C.M. Ewulonu)
Received Date: 2020-06-25
Accepted Date: 2020-08-23
Rev Recd Date: 2020-08-16

Available Online: 2021-02-26

Publish Date: 2021-05-01

Abstract

Abstract

Cellulose nanocrystals isolated from water hyacinth fiber (WHF) have been studied as a reinforcement for polyvinyl alcohol (PVA)-gelatin nanocomposite. Central composite design was used to study and optimize effects of the PVA, gelatin and cellulose nanocrystal (CNC) concentration on tensile strength and elongation of formed films. The results of this study showed that WHF CNC had a diameter range of 20–50 nm produced films reaching 13.8 MPa tensile strength. Thermal stability of the films was improved from 380 ℃ to 385 ℃ in addition of CNCs and maximum storage modulus of 3 GPa were observed when 5 wt% CNC was incorporated. However, water absorption, water vapour permeability (WVP) and moisture uptake of the films decreased in addition of CNC to the PVA-gelatin blends. Moisture uptake decreased from 22.50% to 19.05% while the least WVP when 10 wt% CNC added was 1.64 × 10^–6 g/(m•h•Pa). These results show possibility for industrial application of WHF CNC and PVA-gelatin blends in biodegradable films for on-the-go food wrappers.
- WATER hyacinth,
- Polyvinyl alcohol,
- Gelatin,
- Cellulose nanocrystals,
- Central composite design,
- Packaging films,
- Degradation properties

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References(88)

References

Abral, H., Dalimunthe, M.H., Hartono, J., Efendi, R.P., Asrofi, M., Sugiarti, E., Sapuan, S.M., Park, J.W., Kim, H.J., 2018. Characterization of tapioca starch biopolymer composites reinforced with micro scale water hyacinth fibers. Starch - Stärke 70, 1700287. doi: 10.1002/star.201700287

Agustin, M.B., Ahmmad, B., Alonzo, S.M.M., Patriana, F.M., 2014. Bioplastic based on starch and cellulose nanocrystals from rice straw. J. Reinf. Plast. Compos. 33, 2205–2213. doi: 10.1177/0731684414558325

Agustin, M.B., Ahmmad, B., de Leon, E.R.P., Buenaobra, J.L., Salazar, J.R., Hirose, F., 2013. Starch-based biocomposite films reinforced with cellulose nanocrystals from garlic stalks. Polym. Compos. 34, 1325–1332. doi: 10.1002/pc.22546

Ahmed, S, Ikram, S., 2016. Chitosan and gelatin based biodegradable packaging films with UV-light protection. J. Photochem. Photobiol. B 163, 115–124. doi: 10.1016/j.jphotobiol.2016.08.023

Alves, J.S., dos Reis, K.C., Menezes, E.G., Pereira, F.V., Pereira, J., 2015. Effect of cellulose nanocrystals and gelatin in corn starch plasticized films. Carbohydr. Polym. 115, 215–222. doi: 10.1016/j.carbpol.2014.08.057

Alves, P.M.A., Carvalho, R.A., Moraes, I.C.F., Luciano, C.G., Bittante, A.M.Q.B., Sobral, P.J.A., 2011. Development of films based on blends of gelatin and poly(vinyl alcohol) cross linked with glutaraldehyde. Food Hydrocoll. 25, 1751–1757. doi: 10.1016/j.foodhyd.2011.03.018

Anglès, M.N., Dufresne, A., 2001. Plasticized starch/tunicin whiskers nanocomposite materials. 2. mechanical behavior. Macromolecules34, 2921–2931. doi: 10.1021/ma001555h

Arvanitoyannis, I.S., Nakayama, A., Aiba, S.I., 1998. Chitosan and gelatin based edible films: state diagrams, mechanical and permeation properties. Carbohydr. Polym. 37, 371–382. doi: 10.1016/S0144-8617(98)00083-6

Asrofi, M., Abral, H., Kasim, A., Pratoto, A., 2017. XRD and FTIR studies of nanocrystalline cellulose from water hyacinth (Eichornia crassipes) fiber. J. Metastable Nanocrystalline Mater. 29, 9–16. doi: 10.4028/www.scientific.net/JMNM.29.9

Asrofi, M., Abral, H., Kasim, A., Pratoto, A., Mahardika, M., Hafizulhaq, F., 2018a. Mechanical properties of a water hyacinth nanofiber cellulose reinforced thermoplastic starch bionanocomposite: effect of ultrasonic vibration during processing. Fibers 6, 40. doi: 10.3390/fib6020040

Asrofi, M., Abral, H., Kasim, A., Pratoto, A., Mahardika, M., Park, J.W., Kim, H.J., 2018b. Isolation of nanocellulose from water hyacinth fiber (WHF) produced via digester-sonication and its characterization. Fibers Polym. 19, 1618–1625. doi: 10.1007/s12221-018-7953-1

ASTM Standard D882-09, 2009. Standard Test Method for Tensile Properties of Thin Plastic Sheeting. West Conshohocken, PA: ASTM International. Available at: www.astm.org/standards.

ASTM Standard E96/E96M-05, 2005. Standard Test Method for Water Vapour Transmission of Materials. West Conshohocken, PA: ASTM International. Available at: www.astm.org/standards.

Avella, M., de Vlieger, J.J., Errico, M.E., Fischer, S., Vacca, P., Volpe, M.G., 2005. Biodegradable starch/clay nanocomposite films for food packaging applications. Food Chem. 93, 467–474. doi: 10.1016/j.foodchem.2004.10.024

Avérous, L., Pollet, E., 2012. Biodegradable Polymers. Environmental Silicate Nano-Biocomposites. London: SpringerLondon, 13–39.

Azahari, N.A., Othman, N., Ismail, H., 2011. Biodegradation studies of polyvinyl alcohol/corn starch blend films in solid and solution media. J. Phys. Sci. 22, 15–31. http://www.oalib.com/paper/3089913

Bahy, G.S.E., El-Sayed, E.S., Mahmoud, A.A., Gweily, N.M., 2012. Preparation and characterization of poly vinyl alcohol/gelatin blends. J. Appl. Sci. Res. 8, 3544–3551. http://www.researchgate.net/publication/285810990_Preparation_and_characterization_of_poly_vinyl_alcoholgelatin_blends

Bai, H.Y., Sun, Y.L., Xu, J., Dong, W.F., Liu, X.Y., 2015. Rheological and structural characterization of HA/PVA-SbQ composites film-forming solutions and resulting films as affected by UV irradiation time. Carbohydr. Polym. 115, 422–431. doi: 10.1016/j.carbpol.2014.08.103

Bastarrachea, L., Dhawan, S., Sablani, S.S., 2011. Engineering properties of polymeric-based antimicrobial films for food packaging: a review. Food Eng. Rev. 3, 79–93. doi: 10.1007/s12393-011-9034-8

Belbekhouche, S., Bras, J., Siqueira, G., Chappey, C., Lebrun, L., Khelifi, B., Marais, S., Dufresne, A., 2011. Water sorption behavior and gas barrier properties of cellulose whiskers and microfibrils films. Carbohydr. Polym. 83, 1740–1748. doi: 10.1016/j.carbpol.2010.10.036

Benini, K.C.C.C., Voorwald, H.J.C., Cioffi, M.O.H., Rezende, M.C., Arantes, V., 2018. Preparation of nanocellulose from Imperata brasiliensis grass using Taguchi method. Carbohydr. Polym. 192, 337–346. doi: 10.1016/j.carbpol.2018.03.055

Brinchi, L., Cotana, F., Fortunati, E., Kenny, J.M., 2013. Production of nanocrystalline cellulose from lignocellulosic biomass: technology and applications. Carbohydr. Polym. 94, 154–169. doi: 10.1016/j.carbpol.2013.01.033

Burton, J., van Oosterhout, E., Ensbey, R., Julien, M., 2010. Water Hyacinth (Eichhornia crassipes): Weed of National Significance. New South Wales: Department of Primary Industries.

Cañigueral, N., Vilaseca, F., Méndez, J.A., López, J.P., Barberà, L., Puig, J., Pèlach, M.A., Mutjé, P., 2009. Behavior of biocomposite materials from flax strands and starch-based biopolymer. Chem. Eng. Sci. 64, 2651–2658. doi: 10.1016/j.ces.2009.02.006

Chen, D., Lawton, D., Thompson, M.R., Liu, Q., 2012. Biocomposites reinforced with cellulose nanocrystals derived from potato peel waste. Carbohydr. Polym. 90, 709–716. doi: 10.1016/j.carbpol.2012.06.002

Choo, K., Ching, Y.C., Chuah, C.H., Julai, S., Liou, N.S., 2016. Preparation and characterization of polyvinyl alcohol-chitosan composite films reinforced with cellulose nanofiber. Materials 9, E644. doi: 10.3390/ma9080644

Csiszár, E., Nagy, S., 2017. A comparative study on cellulose nanocrystals extracted from bleached cotton and flax and used for casting films with glycerol and sorbitol plasticisers. Carbohydr. Polym. 174, 740–749. doi: 10.1016/j.carbpol.2017.06.103

Danjaji, I.D., Nawang, R., Ishiaku, U.S., Ismail, H., Mohd Ishak, Z.A.M., 2002. Degradation studies and moisture uptake of sago-starch-filled linear low-density polyethylene composites. Polym. Test. 21, 75–81. doi: 10.1016/S0142-9418(01)00051-4

Dey, K., Ganguli, S., Ghoshal, S., Khan, M.A., Khan, R.A., 2014. Study of the effect of gamma irradiation on the mechanical properties of polyvinyl alcohol based gelatin blend film. OALib 1, 1–10. doi: 10.4236/oalib.1100639

Dufresne, A., 2012. Nanocellulose: From Nature to High Performance Tailored Material. Berlin/Boston: De Gruyter.

El Miri, N., Abdelouahdi, K., Barakat, A., Zahouily, M., Fihri, A., Solhy, A., El Achaby, M., 2015. Bio-nanocomposite films reinforced with cellulose nanocrystals: Rheology of film-forming solutions, transparency, water vapor barrier and tensile properties of films. Carbohydr. Polym. 129, 156–167. doi: 10.1016/j.carbpol.2015.04.051

Ewulonu, C.M., Chukwuneke, J.L., Nwuzor, I.C., Achebe, C.H., 2020. Fabrication of cellulose nanofiber/polypyrrole/polyvinylpyrrolidone aerogels with box-Behnken design for optimal electrical conductivity. Carbohydr. Polym. 235, 116028. doi: 10.1016/j.carbpol.2020.116028

Ewulonu, C.M., Liu, X.R., Wu, M., Huang, Y., 2019. Ultrasound-assisted mild sulphuric acid ball milling preparation of lignocellulose nanofibers (LCNFs) from sunflower stalks (SFS). Cellulose26, 4371–4389. doi: 10.1007/s10570-019-02382-4

Fernandes, S.C.M., Freire, C.S.R., Silvestre, A.J.D., Pascoal Neto, C., Gandini, A., Berglund, L.A., Salmén, L., 2010. Transparent chitosan films reinforced with a high content of nanofibrillated cellulose. Carbohydr. Polym. 81, 394–401. doi: 10.1016/j.carbpol.2010.02.037

Ferreira, F.V., Pinheiro, I.F., Gouveia, R.F., Thim, G.P., Lona, L.M.F., 2017. Functionalized cellulose nanocrystals as reinforcement in biodegradable polymer nanocomposites. Polym. Compos. 39, E9–E29. doi: 10.1002/pc.24583

Firouzi, M., Nguyen, A.V., 2014. Effects of monovalent anions and cations on drainage and lifetime of foam films at different interface approach speeds. Adv. Powder Technol. 25, 1212–1219. doi: 10.1016/j.apt.2014.06.004

Flauzino Neto, W.P., Silvério, H.A., Dantas, N.O., Pasquini, D., 2013. Extraction and characterization of cellulose nanocrystals from agro-industrial residue - Soy hulls. Ind. Crop. Prod. 42, 480–488. doi: 10.1016/j.indcrop.2012.06.041

Ghaderi, J., Hosseini, S.F., Keyvani, N., Gómez-Guillén, M.C., 2019. Polymer blending effects on the physicochemical and structural features of the chitosan/poly(vinyl alcohol)/fish gelatin ternary biodegradable films. Food Hydrocoll. 95, 122–132. doi: 10.1016/j.foodhyd.2019.04.021

Goheen, S.M., Wool, R.P., 1991. Degradation of polyethylene-starch blends in soil. J. Appl. Polym. Sci. 42, 2691–2701. doi: 10.1002/app.1991.070421007

Habibi, Y., Lucia, L.A., Rojas, O.J., 2010. Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem. Rev. 110, 3479–3500. doi: 10.1021/cr900339w

Hajji, S., Chaker, A., Jridi, M., Maalej, H., Jellouli, K., Boufi, S., Nasri, M., 2016. Structural analysis, and antioxidant and antibacterial properties of chitosan-poly (vinyl alcohol) biodegradable films. Environ. Sci. Pollut. Res. Int. 23, 15310–15320. doi: 10.1007/s11356-016-6699-9

Han, J.H., Aristippos, G., 2005. Edible films and coatings: a review. Innovations in Food Packaging. Amsterdam: Elsevier, 239–262.

Heap, B., 2009. Preface. philosophical transactions of the royal society. Biol. Sci. 364, 1971. doi: 10.1098/rstb.2009.0030

Islam, M.S., Rahman, M.M., Gafur, M.A., Mustafa, A.I., Khan, M.A., 2014. Preparation and characterization of cellulose-gelatin nanocomposite isolated from jute for biomedical application. Mater. Sci. : Indian J. 11, 105–112. doi: 10.1186/2193-1801-3-105

Ismaiel, A.M., Salman, H.M.A., Said, H.M., Abd El-sadek, M.S., 2018. Synthesis and characterization of biodegradable polyvinyl alcohol/gelatin polymer blend film based on gamma radiation. Indo Am. J. Pharm. Sci. 5, 3345–3352.

Jiang, Y., Li, Y., Chai, Z., Leng, X., 2010. Study of the physical properties of whey protein isolate and gelatin composite films. J. Agric. Food Chem. 58, 5100–5108. doi: 10.1021/jf9040904

Kanatt, S.R., Tanvi, J., Kirti, S., & Chawla, S.P., 2017. PVA-Gelatin films incorporated with tomato pulp: a potential primary food packaging film. Int. J. Curr. Microbiol. Appl. Sci. 6, 1428–1441. doi: 10.20546/ijcmas.2017.611.170

Kanmani, P., Rhim, J.W., 2014. Properties and characterization of bionanocomposite films prepared with various biopolymers and ZnO nanoparticles. Carbohydr. Polym. 106, 190–199. doi: 10.1016/j.carbpol.2014.02.007

Kargarzadeh, H., Johar, N., Ahmad, I., 2017. Starch biocomposite film reinforced by multiscale rice husk fiber. Compos. Sci. Technol. 151, 147–155. doi: 10.1016/j.compscitech.2017.08.018

Kawai, F., Hu, X.P., 2009. Biochemistry of microbial polyvinyl alcohol degradation. Appl. Microbiol. Biotechnol. 84, 227–237. doi: 10.1007/s00253-009-2113-6

Kerfoot, D.G.E. N, 2012. In Ullmann's Encyclopedia Of Industrial Chemistry. Weinheim, Germany: Wiley-VCH verlag GmbH & co. KGaA.

Kumar, A., Negi, Y.S., Choudhary, V., Bhardwaj, N.K., 2015. Morphological and mechanical properties of cellulose nanocrystals reinforced poly (vinyl alcohol) bio-composite films. Trends Carbohydr. Res. 7, 23–30. doi: 10.3923/ppj.2015.23.30

Kumar, A., Singh Negi, Y., Choudhary, V., Kant Bhardwaj, N., 2020. Characterization of cellulose nanocrystals produced by acid-hydrolysis from sugarcane bagasse as agro-waste. J. Mater. Phys. Chem. 2, 1–8. doi: 10.1080/1354750x.2019.1691657

Kumar, S., Shukla, A., Baul, P.P., Mitra, A., Halder, D., 2018. Biodegradable hybrid nanocomposites of chitosan/gelatin and silver nanoparticles for active food packaging applications. Food Packag. Shelf Life 16, 178–184. doi: 10.1016/j.fpsl.2018.03.008

Lu, P., Hsieh, Y.L., 2012. Preparation and characterization of cellulose nanocrystals from rice straw. Carbohydr. Polym. 87, 564–573. doi: 10.1016/j.carbpol.2011.08.022

Luo, J., Chang, H.B., Bakhtiary Davijani, A.A., Liu, H.C., Wang, P.H., Moon, R.J., Kumar, S., 2017. Influence of high loading of cellulose nanocrystals in polyacrylonitrile composite films. Cellulose 24, 1745–1758. doi: 10.1007/s10570-017-1219-8

Ma, X.H., Cheng, Y.J., Qin, X.L., Guo, T., Deng, J., Liu, X., 2017. Hydrophilic modification of cellulose nanocrystals improves the physicochemical properties of cassava starch-based nanocomposite films. LWT 86, 318–326. doi: 10.1016/j.lwt.2017.08.012

Mangaraj, S., Goswami, T.K., Mahajan, P.V., 2009. Applications of plastic films for modified atmosphere packaging of fruits and vegetables: a review. Food Eng. Rev. 1, 133–158. doi: 10.1007/s12393-009-9007-3

Mariano, M., Cercená, R., Soldi, V., 2016. Thermal characterization of cellulose nanocrystals isolated from sisal fibers using acid hydrolysis. Ind. Crop. Prod. 94, 454–462. doi: 10.1016/j.indcrop.2016.09.011

Mochochoko, T., Oluwafemi, O.S., Jumbam, D.N., Songca, S.P., 2013. Green synthesis of silver nanoparticles using cellulose extracted from an aquatic weed; water hyacinth. Carbohydr. Polym. 98, 290–294. doi: 10.1016/j.carbpol.2013.05.038

Mukherjee, R., Nandi, B., 2004. Improvement of in vitro digestibility through biological treatment of water hyacinth biomass by two Pleurotus species. Int. Biodeterior. Biodegrad. 53, 7–12. doi: 10.1016/S0964-8305(03)00112-4

Naduparambath, S., Sreejith, M.P., Jinitha, T.V., Shaniba, V., Aparna, K.B., Purushothaman, E., 2018. Development of green composites of poly (vinyl alcohol) reinforced with microcrystalline cellulose derived from sago seed shells. Polym. Compos. 39, 3033–3039. doi: 10.1002/pc.24307

Nigam, J.N., 2002. Bioconversion of water-hyacinth (Eichhornia crassipes) hemicellulose acid hydrolysate to motor fuel ethanol by xylose-fermenting yeast. J Biotechno l97, 107–116. doi: 10.1016/S0168-1656(02)00013-5

Niranjana Prabhu, T., Prashantha, K., 2018. A review on present status and future challenges of starch based polymer films and their composites in food packaging applications. Polym. Compos. 39, 2499–2522. doi: 10.1002/pc.24236

Noshirvani, N., Hong, W., Ghanbarzadeh, B., Fasihi, H., Montazami, R., 2018. Study of cellulose nanocrystal doped starch-polyvinyl alcohol bionanocomposite films. Int. J. Biol. Macromol. 107, 2065–2074. doi: 10.1016/j.ijbiomac.2017.10.083

Otoni, C.G., Avena-Bustillos, R.J., Azeredo, H.M.C., Lorevice, M.V., Moura, M.R., Mattoso, L.H.C., McHugh, T.H., 2017. Recent advances on edible films based on fruits and vegetables—a review. Compr. Rev. Food Sci. Food Saf. 16, 1151–1169. doi: 10.1111/1541-4337.12281

Patricia Miranda, S., Garnica, O., Lara-Sagahon, V., Cárdenas, G., 2004. Water vapor permeability and mechanical properties of chitosan composite films. J. Chil. Chem. Soc. 49: 173–178. http://www.oalib.com/paper/878337

Pitaloka, A.B., Saputra, A.H., Nasikin, M., 2013. Water hyacinth for superabsorbent polymer material. World Appl. Sci. J. 22, 747–754. http://www.researchgate.net/publication/286280771_Water_hyacinth_for_superabsorbent_polymer_material

Popescu, M.C., Dogaru, B.I., Goanta, M., Timpu, D., 2018. Structural and morphological evaluation of CNC reinforced PVA/starch biodegradable films. Int. J. Biol. Macromol. 116, 385–393. doi: 10.1016/j.ijbiomac.2018.05.036

Popescu, M.C., Dogaru, B.I., Popescu, C.M., 2017. The influence of cellulose nanocrystals content on the water sorption properties of bio-based composite films. Mater. Des. 132, 170–177. doi: 10.1016/j.matdes.2017.06.067

Qi, L.F., Xu, Z.R., Jiang, X., Hu, C.H., Zou, X.F., 2004. Preparation and antibacterial activity of chitosan nanoparticles. Carbohydr. Res. 339, 2693–2700. doi: 10.1016/j.carres.2004.09.007

Rahman, M., Dey, K., Parvin, F., Sharmin, N., Khan, R.A., Sarker, B., Nahar, S., Ghoshal, S., Khan, M.A., Billah, M.M., Zaman, H.U., Chowdhury, A.M.S., 2011. Preparation and characterization of gelatin-based PVA film: effect of gamma irradiation. Int. J. Polym. Mater. Polym. Biomater. 60, 1056–1069. doi: 10.1080/00914037.2010.551365

Ramos, M., Jiménez, A., Garrigós, M.C., 2016. Carvacrol-Based Films. Antimicrobial Food Packaging. Amsterdam: Elsevier, 329–338.

Rosa, M.F., Medeiros, E.S., Malmonge, J.A., Gregorski, K.S., Wood, D.F., Mattoso, L.H.C., Glenn, G., Orts, W.J., Imam, S.H., 2010. Cellulose nanowhiskers from coconut husk fibers: effect of preparation conditions on their thermal and morphological behavior. Carbohydr. Polym. 81, 83–92. doi: 10.1016/j.carbpol.2010.01.059

Said, H.M., 2013. Development of films based on poly (vinyl alcohol)/gelatin blends cross linked by electron beam irradiation. Arab J. Nucl. Sci. Appl. 46, 70–78. http://www.researchgate.net/publication/303255768_Development_of_films_based_on_poly_vinyl_alcoholgelatin_blends_cross_linked_by_electron_beam_irradiation

Sajjan, A.M., Naik, M.L., Kulkarni, A.S., Fazal-E-Habiba Rudgi, U., M, A., Shirnalli, G.G., A, S., Kalahal, P.B., 2020. Preparation and characterization of PVA-Ge/PEG-400 biodegradable plastic blend films for packaging applications. Chem. Data Collect. 26, 100338. doi: 10.1016/j.cdc.2020.100338

Salisu, A.A., 2012. Preparation and characterization of biodegradable poly(vinyl alcohol)/starch blends. Chem. Search J. 3, 34–37. http://www.ajol.info/index.php/csj/article/view/115862

Saurabh, C.K., Dungani, R., Owolabi, A.F., Atiqah, N.S., Zaidon, A., Sri Aprilia, N.A., Md Sarker, Z., Abdul Khalil, H.P.S., 2016. Effect of hydrolysis treatment on cellulose nanowhiskers from oil palm (Elaeis guineesis) fronds: morphology, chemical, crystallinity, and thermal characteristics. BioResources 11, 6742–6755. http://www.researchgate.net/publication/304750066_Effect_of_Hydrolysis_Treatment_on_Cellulose_Nanowhiskers_from_Oil_Palm_Elaeis_guineesis_Fronds_Morphology_Chemical_Crystallinity_and_Thermal_Characteristics

Segal, L., Creely, J.J., Martin, A.E. Jr, Conrad, C.M., 1959. An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text. Res. J. 29, 786–794. doi: 10.1177/004051755902901003

Singh, S., Gaikwad, K.K., Lee, Y.S., 2018. Antimicrobial and antioxidant properties of polyvinyl alcohol bio composite films containing seaweed extracted cellulose nano-crystal and basil leaves extract. Int. J. Biol. Macromol. 107, 1879–1887. doi: 10.1016/j.ijbiomac.2017.10.057

Sionkowska, A., 2011. Current research on the blends of natural and synthetic polymers as new biomaterials: review. Prog. Polym. Sci. 36, 1254–1276. doi: 10.1016/j.progpolymsci.2011.05.003

Slavutsky, A.M., Bertuzzi, M.A., 2014. Water barrier properties of starch films reinforced with cellulose nanocrystals obtained from sugarcane bagasse. Carbohydr. Polym. 110, 53–61. doi: 10.1016/j.carbpol.2014.03.049

Sorrentino, A., Gorrasi, G., Vittoria, V., 2007. Potential perspectives of bio-nanocomposites for food packaging applications. Trends Food Sci. Technol. 18, 84–95. doi: 10.1016/j.tifs.2006.09.004

Tang, X.Z., Kumar, P., Alavi, S., Sandeep, K.P., 2012. Recent advances in biopolymers and biopolymer-based nanocomposites for food packaging materials. Crit. Rev. Food Sci. Nutr. 52, 426–442. doi: 10.1080/10408398.2010.500508

Wise, L.E., Murphy, M., A.A., D., 1946. Chlorite holocellulose, its fractionation and bearing on summative wood analysis and on studies on the hemicelluloses. Paper 122, 35. http://ci.nii.ac.jp/naid/10006323318

Xu, Y.X., Scales, A., Jordan, K., Kim, C., Sismour, E., 2017. Starch nanocomposite films incorporating grape pomace extract and cellulose nanocrystal. J. Appl. Polym. Sci. 134, 44438. doi: 10.1002/app.44438

Yadollahi, M., Namazi, H., Barkhordari, S., 2014. Preparation and properties of carboxymethyl cellulose/layered double hydroxide bionanocomposite films. Carbohydr. Polym. 108, 83–90. doi: 10.1016/j.carbpol.2014.03.024

Zhou, L., He, H., Jiang, C., Ma, L., Yu, P., 2017. Cellulose nanocrystals from cotton stalk for reinforcement of poly (vinyl alcohol) composites. Cellulose Chem. Technol. 51, 109–119. http://smartsearch.nstl.gov.cn/paper_detail.html?id=07c13e1ad3c76d81d8adddb81dc45321

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