Volume 5 Issue 3
Aug.  2020
Turn off MathJax
Article Contents
Hongyun Qian, Jiake Wang, Lifeng Yan. Synthesis of lignin-poly(N-methylaniline)-reduced graphene oxide hydrogel for organic dye and lead ions removal[J]. Journal of Bioresources and Bioproducts, 2020, 5(3): 204-210. doi: 10.1016/j.jobab.2020.07.006
Citation: Hongyun Qian, Jiake Wang, Lifeng Yan. Synthesis of lignin-poly(N-methylaniline)-reduced graphene oxide hydrogel for organic dye and lead ions removal[J]. Journal of Bioresources and Bioproducts, 2020, 5(3): 204-210. doi: 10.1016/j.jobab.2020.07.006

Synthesis of lignin-poly(N-methylaniline)-reduced graphene oxide hydrogel for organic dye and lead ions removal

doi: 10.1016/j.jobab.2020.07.006
More Information
  • Author Bio:

    E-mail addresses: lfyan@ustc.edu.cn

  • Corresponding author: Lifeng Yan, E-mail addresses: lfyan@ustc.edu.cn
  • Received Date: 2020-02-11
  • Accepted Date: 2020-03-25
  • Publish Date: 2020-08-01
  • Lignin is one of the major contents of lignocellulose and can be used as feedstock for adsorbent materials for wastewater treatment. Here, a lignin-poly(N-methylaniline)-graphene oxide (lignin-PNMA-rGO) hydrogel has been prepared by a two-step method, microspheres of lignin-PNMA was synthesis by the polymerization of NMA monomer in the presence of lignin in aqueous solution, and then they were encapsulated by the as-prepared reduced graphene oxide (GO) hydrogel via a reduction induced self-assembly of the GO nanosheets.The scanning electron microscopy (SEM), Fourier transform infrared (FT-IR), X-ray diffraction (XRD), and UV-Vis studies have been carried out and revealed that the formation of the 3D porous nanocomposite hydrogel with multilevel structures and sufficient active sites. The lignin-PNMA-rGO adsorbent exhibited high adsorption capacity for both organic dye methylene blue (MB, 201.7 mg/g) and Pb2+ ion (753.5 mg/g). The new lignin-based adsorbent is a low-cost, environmentally benign, which is an attractive adsorbent for wastewater treatment.

     

  • loading
  • Chen, J.C., Eraghi Kazzaz, A., AlipoorMazandarani, N., Hosseinpour Feizi, Z., Fatehi, P., 2018. Production of flocculants, adsorbents, and dispersants from lignin. Molecules 23, 868. doi: 10.3390/molecules23040868
    de Araújo Padilha, C.E., da Costa Nogueira, C., de Santana Souza, D.F., de Oliveira, J.A., dos Santos, E.S., 2020. Organosolv lignin/Fe3O4 nanoparticles applied as a β; -glucosidase immobilization support and adsorbent for textile dye removal. Ind. Crop. Prod. 146, 112167. doi: 10.1016/j.indcrop.2020.112167
    Gao, D.W., Hu, Q., Pan, H.Y., Jiang, J.P., Wang, P., 2015. High-capacity adsorption of aniline using surface modification of lignocellulose-biomass jute fibers. Bioresour. Technol. 193, 507-512. doi: 10.1016/j.biortech.2015.06.138
    Ge, Y.Y., Li, Z.L., 2018. Application of lignin and its derivatives in adsorption of heavy metal ions in water:a review. ACS Sustainable Chem. Eng. 6, 7181-7192. doi: 10.1021/acssuschemeng.8b01345
    Godwin, P.M., Pan, Y., Xiao, H., Afzal, M.T., 2019. Progress in preparation and application of modified biochar for improving heavy metal ion removal from wastewater. J. Bioresour. Bioprod. 4, 31-42.
    He, Z.W., Lü, Q.F., Zhang, J.Y., 2012. Facile preparation of hierarchical polyaniline-lignin composite with a reactive silver-Ion adsorbability. ACS Appl. Mater. Interfaces 4, 369-374. doi: 10.1021/am201447s
    Jiang, C.L., Wang, X.H., Qin, D.M., Da, W.X., Hou, B.X., Hao, C., Wu, J.B., 2019. Construction of magnetic lignin-based adsorbent and its adsorption properties for dyes. J. Hazard. Mater. 369, 50-61. doi: 10.1016/j.jhazmat.2019.02.021
    Jiang, S.H., Wu, J.X., Zhou, J., Lü, Q.F., 2018. High-performance reactive silver-Ion adsorption and reductive performance of poly(N -methylaniline). Adv. Polym. Technol. 37, 1486-1495. doi: 10.1002/adv.21807
    Li, F.F., Wang, X.L., Yuan, T.Q., Sun, R.C., 2016. A lignosulfonate-modified graphene hydrogel with ultrahigh adsorption capacity for Pb(ⅱ) removal. J. Mater. Chem. A 4, 11888-11896. doi: 10.1039/C6TA03779H
    Lü, Q.F., Luo, J.J., Lin, T.T., Zhang, Y.Z., 2014. Novel lignin-poly(N-methylaniline) composite sorbent for silver Ion removal and recovery. ACS Sustainable Chem. Eng. 2, 465-471. doi: 10.1021/sc400475r
    Lü, Q.F., Zhang, J.Y., Yang, J., He, Z.W., Fang, C.Q., Lin, Q.L., 2013. Self-assembled poly(N-methylaniline)-lignosulfonate spheres:from silver-Ion adsorbent to antimicrobial material. Chem. Eur. J. 19, 10935-10944. doi: 10.1002/chem.201204113
    Ma, M.S., Liu, Z., Hui, L.F., Shang, Z., Yuan, S.Y., Dai, L., Liu, P.T., Liu, X.L., Ni, Y.H., 2019. Lignin-containing cellulose nanocrystals/sodium alginate beads as highly effective adsorbents for cationic organic dyes. Int. J. Biol. Macromol. 139, 640-646. doi: 10.1016/j.ijbiomac.2019.08.022
    Mary, A.S., Sheem Mers, S.V., 2019. Synthesis and characterization of electroactive poly (N-methylaniline-Co-O-toluidine). Chem. Sci. Trans. 8, 347-358.
    Musielak, M., Gagor, A., Zawisza, B., Talik, E., Sitko, R., 2019. Graphene oxide/carbon nanotube membranes for highly efficient removal of metal ions from water. ACS Appl. Mater. Interfaces 11, 28582-28590. doi: 10.1021/acsami.9b11214
    Su, H., Bi, Z.H., Ni, Y., Yan, L.F., 2019. One-pot degradation of cellulose into carbon dots and organic acids in its homogeneous aqueous solution. Green Energy Environ. 4, 391-399. doi: 10.1016/j.gee.2019.01.009
    Tan, T.C.N., Sen, T.K., 2020. Aqueous-phase methylene blue (MB) dye removal by mixture of Eucalyptus bark (EB) biomass and Kaolin clay (KC) adsorbents:kinetics, thermodynamics, and isotherm modeling. Sep. Sci. Technol. 55, 1036-1050. doi: 10.1080/01496395.2019.1580734
    Wang, H.F., Song, Y.Q., Ye, X.X., Wang, H., Liu, W.S., Yan, L.F., 2018. Asymmetric supercapacitors assembled by dual spinel Ferrites@Graphene nanocomposites as electrodes. ACS Appl. Energy Mater. 1, 3206-3215. doi: 10.1021/acsaem.8b00433
    Wang, H.F., Wu, J., Qiu, J., Zhang, K.F., Shao, J.W., Yan, L.F., 2019a. In situ formation of a renewable cellulose hydrogel electrolyte for high-performance flexible all-solid-state asymmetric supercapacitors. Sustain. Energy Fuels 3, 3109-3115. doi: 10.1039/C9SE00339H
    Wang, H.F., Zhang, K.F., Song, Y.Q., Qiu, J., Wu, J., Yan, L.F., 2019b. MnCo2S4 nanoparticles anchored to N- and S-codoped 3D graphene as a prominent electrode for asymmetric supercapacitors. Carbon 146, 420-429. doi: 10.1016/j.carbon.2019.02.035
    Yan, L.F., Chen, J., Bangal, P.R., 2007. Dissolving cellulose in a NaOH/thiourea aqueous solution:a topochemical investigation. Macromol. Biosci. 7, 1139-1148. doi: 10.1002/mabi.200700072
    Yan, L.F., Shuai, Q., Gong, X.L., Gu, Q., Yu, H.Q., 2009. Synthesis of microporous cationic hydrogel of hydroxypropyl cellulose (HPC) and its application on anionic dye removal. CLEAN-Soil Air Water 37, 392-398. doi: 10.1002/clen.200900006
    Yang, J., Wu, J.X., Lü, Q.F., Lin, T.T., 2014. Facile preparation of lignosulfonate-graphene oxide-polyaniline ternary nanocomposite as an effective adsorbent for Pb(Ⅱ) ions. ACS Sustainable Chem. Eng. 2, 1203-1211. doi: 10.1021/sc500030v
    Yang, Y., Deng, Y.H., Tong, Z., Wang, C.Y., 2014. Renewable lignin-based xerogels with self-cleaning properties and superhydrophobicity. ACS Sustainable Chem. Eng. 2, 1729-1733. doi: 10.1021/sc500250b
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(9)

    Article Metrics

    Article views (920) PDF downloads(48) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return