Volume 6 Issue 3
Jul.  2021
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Article Contents
Fanglin Dai, Junrong Luo, Shenghui Zhou, Xingzhen Qin, Detao Liu, Haisong Qi. Porous Hafnium-Containing Acid/Base Bifunctional Catalysts for Efficient Upgrading of Bio-Derived Aldehydes[J]. Journal of Bioresources and Bioproducts, 2021, 6(3): 243-253. doi: 10.1016/j.jobab.2021.04.006
Citation: Fanglin Dai, Junrong Luo, Shenghui Zhou, Xingzhen Qin, Detao Liu, Haisong Qi. Porous Hafnium-Containing Acid/Base Bifunctional Catalysts for Efficient Upgrading of Bio-Derived Aldehydes[J]. Journal of Bioresources and Bioproducts, 2021, 6(3): 243-253. doi: 10.1016/j.jobab.2021.04.006

Porous Hafnium-Containing Acid/Base Bifunctional Catalysts for Efficient Upgrading of Bio-Derived Aldehydes

doi: 10.1016/j.jobab.2021.04.006
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  • Corresponding author: E-mail addresses: xzhqin2009@163.com (X. Qin); E-mail addresses: qihs@scut.edu.cn (H. Qi)
  • Received Date: 2020-07-20
  • Accepted Date: 2020-09-28
  • Rev Recd Date: 2020-09-20
  • Available Online: 2021-04-17
  • Publish Date: 2021-08-01
  • Novel organic-inorganic hybrids were synthesized by using HfCl4 and organic ligand 1H-pyrrole-2, 5-dicarboxylic acid (PDCA) via a simple hydrothermal method. The as-prepared Hf-PDCA were characterized by various techniques, such as electron microscope, N2 adsorption/desorption, and X-ray photoelectron spectroscopy. Among them, the porous and nitrogen-containing Hf-PDCA as heterogeneous acid/base bifunctional catalyst was then applied to the catalytic hydrogenation of furfural to produce furfuryl alcohol (FFA). It exhibited excellent catalytic performance, with high conversion (98.8%) and selectivity (98.5%) by using 2-propanol as hydrogen source under a relatively mild condition. Moreover, the Hf-PDCA has strong stability and durability, and can be recovered after the catalyst reaction. In addition, the Hf-PDCA as catalyst can be extended to fabricate corresponding alcohols by catalytic conversion of other biomass derived aldehydes.

     

  • 1 Fanglin Dai and Junrong Luo contributed equally to this work and should be considered co-first authors.
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