Volume 9 Issue 4
Nov.  2024
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I Dewa Gede Arsa Putrawan, Adli Azharuddin. Valorization of palm oil refining by-product for organotin mercaptide as a polyvinyl chloride thermal stabilizer: Synthesis, efficacy and comparison to mixed metal stearate[J]. Journal of Bioresources and Bioproducts, 2024, 9(4): 565-576. doi: 10.1016/j.jobab.2024.06.001
Citation: I Dewa Gede Arsa Putrawan, Adli Azharuddin. Valorization of palm oil refining by-product for organotin mercaptide as a polyvinyl chloride thermal stabilizer: Synthesis, efficacy and comparison to mixed metal stearate[J]. Journal of Bioresources and Bioproducts, 2024, 9(4): 565-576. doi: 10.1016/j.jobab.2024.06.001

Valorization of palm oil refining by-product for organotin mercaptide as a polyvinyl chloride thermal stabilizer: Synthesis, efficacy and comparison to mixed metal stearate

doi: 10.1016/j.jobab.2024.06.001
  • Publish Date: 2024-06-03
  • Organotin mercaptide-based thermal stabilizer is recognized for its effectiveness in enhancing thermal stability of polyvinyl chloride (PVC). In this study, we synthesized an organotin mercaptide-based thermal stabilizer from palm fatty acid distillate, which is a by-product of palm oil refining process, and then evaluated its thermal stabilizing effects on PVC and compared its efficacy and economics to those of mixed metal stearate. The synthesized thermal stabilizer manifests as methyltin mercaptoethyl carboxylate sulfides. Both dehydrochlorination and two-roll mill discoloration tests have demonstrated the high efficacy of the resulting thermal stabilizer in stabilizing PVC, surpassing the performance of mixed metal stearate, as evidenced by the lower dosage required. The synthesized PVC thermal stabilizer not only provides effective stabilization but also presents a competitive viable alternative.

     

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  • [1]
    Barbara, S., 2004. Infrared Spectroscopy: Fundamentals and Application. Chichester: John Wiley & Sons.
    [2]
    Brecker, L.R., 1981. Structure-performance relationships in organotin mercaptide stabilizers. Pure Appl. Chem. 53, 577-582.
    [3]
    Chang, A.S., Sherazi, S.T.H., Kandhro, A.A., Mahesar, S.A., Chang, F., Shah, S.N., Laghari, Z.H., Panhwar, T., 2016. Characterization of palm fatty acid distillate of different oil processing industries of Pakistan. J. Oleo Sci. 65, 897-901.
    [4]
    FSSAI, 2015. Manual of Methods of Analysis of Foods: Oils and Fats. New Delhi: Food Safety and Standards Authority of India.
    [5]
    Ge, X.L., Culyba, E.K., Grinnell, C.L., Zestos, A.G., Starnes, W.H. Jr, 2007. Mechanism of action and effectiveness of ester thiols as thermal stabilizers for poly(vinyl chloride). J. Vinyl Addit. Technol. 13, 170-175.
    [6]
    Han, W.Y., Zhang, M.Q., Kong, Y.F., Li, D.G., Liu, L.H., Tang, S.Y., Ding, J., Liu, S.M., 2020. Pentaerythritol stearate ester-based tin (II) metal alkoxides: a tri-functional organotin as poly (vinyl chloride) thermal stabilizers. Polym. Degrad. Stab. 175, 109129.
    [7]
    Knezevic, M., Katsikas, L., Popovic, I., 2005. The synthesis and characterization of 2-mercaptoethyl methacrylate. Hemijska Ind. 59, 321-323.
    [8]
    Kugele, T.G., Conroy, G.M., 1991. A review of the relationship of tin content and ligand structure on stability of rigid PVC compositions. J. Vinyl Addit. Technol. 13, 47-49.
    [9]
    Lam, J.E., Mohamed, A.R., Kay Lup, A.N., Koh, M.K., 2022. Palm fatty acid distillate derived biofuels via deoxygenation: properties, catalysts and processes. Fuel Process. Technol. 236, 107394.
    [10]
    Lawer-Yolar, G., Dawson-Andoh, B., Atta-Obeng, E., 2021. Synthesis of biodiesel from tall oil fatty acids by homogeneous and heterogeneous catalysis. Sustain. Chem. 2, 206-221.
    [11]
    Li, D.G., Liu, P.J., 2022. Trends and prospects for thermal stabilizers in polyvinyl chloride. J. Vinyl Addit. Technol. 28, 669-688.
    [12]
    O'Brien, R.D., 2009. Fat and Oils: Formulating and Processing for Applications. Florida: CRC Press.
    [13]
    Othman, N., Chong, G.H., Azman, E.M., Suleiman, N., 2022. Effect of process variables in supercritical carbon dioxide extraction of tocotrienols from hydrolyzed palm fatty acid distillate (PFAD). J. Food Process. Preserv. 46, e16533.
    [14]
    Putrawan, I.A., Azharuddin, A., Jumrawati, J., 2023. Preparing epoxidized vegetable oil from waste generated by the kapok fiber industry and assessing its thermal stabilization effect as a co-stabilizer for polyvinyl chloride. Heliyon 9, e19624.
    [15]
    Putrawan, I.D.G.A., Azharuddin, A., Arum, K.R., Adityawarman, D., Rahim, D.A., 2018. Synthesis of mercapto ethyl ester of palm fatty acid distillate. MATEC Web Conf. 156, 06010.
    [16]
    Schiller, M., 2015. PVC Additives: Performance, Chemistry, Developments, and Sustainability. München: Carl Hanser Verlag GmbH & Co. KG.
    [17]
    Shen, G.H., Zhao, Y.H., Ma, M.X., Wang, Y.L., Hao, X.Y., Yuan, G.D., 2023. Enhancing the initial whiteness and long-term thermal stability of polyvinyl chloride by utilizing layered double hydroxides with low surface basicity. Polymers (Basel) 15, 1043.
    [18]
    Shubbar, S.D.A., Dhiaa, A.H., Egzar, H.K., 2023. Investigating the role of different stabilizers of PVCs by using a torque rheometer. Open Eng. 13, 423.
    [19]
    Tay, B., Ping, Y., Yusof, M., 2009. Characteristics and properties of fatty acid distillates from palm oil. Oil Palm Bull. 59, 5-11.
    [20]
    Vevere, L., Fridrihsone, A., Kirpluks, M., Cabulis, U., 2020. A review of wood biomass-based fatty acids and rosin acids use in polymeric materials. Polymers (Basel) 12, 2706.
    [21]
    Wang, M., Xu, J.Y., Wu, H., Guo, S.Y., 2006. Effect of pentaerythritol and organic tin with calcium/zinc stearates on the stabilization of poly(vinyl chloride). Polym. Degrad. Stab. 91, 2101-2109.
    [22]
    Widiputri, D.I., Jayaratana, A., Legowo, E.H., 2020. Improving the methodology of squalene extraction from palm fatty acid distillate (PFAD) through enhanced pre-treatment process. J. Funct. Food Nutraceutical 1, 101-110.
    [23]
    Wilting, H., Hanemaaijer, A., 2014. Share of Raw Material Costs in Total Production Costs. The Hague: Netherlands Environmental Assessment Agency.
    [24]
    Ye, W., Wen, Z., Chen, C., Zhang, M., Liao, Z., 2022. Cyanoacetylurea as a thermal stabilizer for poly(vinyl chloride). Polym. Plast. Technol. Mater. 61, 1223-1232.
    [25]
    Yeong, S.P., Chan, Y.S., Law, M.C., Ling, J.K.U., 2022. Improving cold flow properties of palm fatty acid distillate biodiesel through vacuum distillation. J. Bioresour. Bioprod. 7, 43-51.
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