| Citation: | Yufan Feng, Yaqian Yu, Xueyi Zhou, Tingting Xu, Huining Xiao, Zhiguo Wang, Hongqi Dai, Huiyang Bian. Scalable polyaniline-bridged multifunctional bamboo fiber/carbon nanotubes composite foam via ambient drying for thermal protection and electromagnetic shielding[J]. Journal of Bioresources and Bioproducts, 2026, 11(5): 100299. doi: 10.1016/j.jobab.2026.100299 |
The scalable development of sustainable, high-performance cellulose foams is often impeded by energy-intensive drying processes and the structural vulnerability of porous networks under ambient conditions. In this paper, we report an ambient-pressure drying strategy to fabricate polyaniline-bridged multifunctional bamboo fiber (BF)/multiwalled carbon nanotubes (MWCNTs) composite foam. By employing 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) oxidized cellulose nanofibril (TOCNF) to uniformly disperse MWCNTs within the BF network, a hierarchical porous architecture with mechanical robustness and high electrical conductivity was constructed through ice-templating, Zn2+ crosslinking, and hydrogen bonding, effectively resisting capillary-force-induced collapse without the need for freeze-drying or solvent exchange. The optimized Zn2+ crosslinked polyaniline-bridged multi-walled carbon nanotubes/bamboo fiber/TOCNF composite foam (Zn-P3M4BC1) exhibited an exceptional electromagnetic interference shielding effectiveness of 61.56 dB, with an absolute specific shielding efficiency (SSE/d) of 2375.2 dB·cm2/g, surpassing most reported carbon-based and polyaniline (PANI)-based aerogels. Furthermore, the synergistic interplay between MWCNTs/PANI and phytic acid endowed composite foam with excellent flame retardancy (limiting oxygen index = 56.8%), low thermal conductivity (0.085 W/(m·K)), and reliable electrothermal and infrared camouflage performance. Overall, this work provides a scalable and energy-efficient route to multifunctional cellulose-based foams for electromagnetic protection, thermal insulation and adaptive infrared camouflage.
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