Volume 11 Issue 5
Oct.  2026
Turn off MathJax
Article Contents
Mohammad Mahbubul Hassan. Advances in manufacturing sustainable textile fibers from chitin and its derivatives: Spinning methods, fiber functional properties, biodegradability, and environmental impacts[J]. Journal of Bioresources and Bioproducts, 2026, 11(5): 100300. doi: 10.1016/j.jobab.2026.100300
Citation: Mohammad Mahbubul Hassan. Advances in manufacturing sustainable textile fibers from chitin and its derivatives: Spinning methods, fiber functional properties, biodegradability, and environmental impacts[J]. Journal of Bioresources and Bioproducts, 2026, 11(5): 100300. doi: 10.1016/j.jobab.2026.100300

Advances in manufacturing sustainable textile fibers from chitin and its derivatives: Spinning methods, fiber functional properties, biodegradability, and environmental impacts

doi: 10.1016/j.jobab.2026.100300
Funds:

This work was financially supported by the Natural Environment Research Council NERC of the UK Research and Innovation UKRI through the ‘Future Fibers Networking’ project (No. NE/Y003985/1).

  • Received Date: 2026-06-25
  • Accepted Date: 2026-08-24
  • Rev Recd Date: 2026-08-20
  • Available Online: 2026-11-03
  • Publish Date: 2026-09-05
  • Most of the current textiles are made from non-renewable, non-biodegradable synthetic fibers that are a source of microplastic pollution. The alternative biodegradable natural fibers have not only limited production but also have high energy and water usage along with high carbon footprints. Chitin has immense possibilities to replace non-biodegradable synthetic polymers for textile fiber manufacturing because of its abundance, biodegradability, and many beneficial functional properties. Despite its abundance, its utilization in textile fiber manufacturing is limited because of its insolubility and performance issues. Spinning of fibers from chitin derivatives for textile production was mainly studied by wet and dry-jet wet spinning methods using a range of solvents including ionic liquids, spinning dope additives (other polymers, nanoparticles), and various coagulation baths that considerably enhanced fiber performance and functionalities. Recent advancements enabled manufacturing fibers by gel spinning directly from chitin without any derivatization, which produced fibers with strength comparable to several natural fibers. This review discusses chitin and its derivatives as fiber-forming polymers, spinning methods, various solvents used, spinning methods, fiber crosslinking, and spinning dope additives to enhance the mechanical and functional properties of the resultant fibers. The discussion also includes the toxicity and biodegradation of chitin fiber, carbon footprints, and future directions in advancing its application toward sustainable fiber production. The key limitation of the review article is the consideration of only published peer-reviewed journal articles but no patent specifications. A limited number of published articles discussed the structure-property relationship of fibers produced from chitin and its derivatives. The true comparison of various performances of fibers produced by various methods was difficult due to different conditions used by different research groups. It is possible to manufacture textile fibers with strength comparable to many natural fibers by selecting the right source of chitin and its derivatives.

     

  • loading
  • [1]
    Abdelgawad, A.M., Hudson, S.M., Rojas, O.J., 2014. Antimicrobial wound dressing nanofiber mats from multicomponent (chitosan/silver-NPs/polyvinyl alcohol) systems. Carbohydr. Polym. 100, 166-178.
    [2]
    Adusumali, R.B., Reifferscheid, M., Weber, H., Roeder, T., Sixta, H., Gindl, W., 2006. Mechanical properties of regenerated cellulose fibers for composites. Macromol. Symp. 244, 119-125.
    [3]
    Alay, E., Duran, K., Korlu, A., 2016. A sample work on green manufacturing in textile industry. Sustain. Chem. Pharm. 3, 39-46.
    [4]
    Albanna, M.Z., Bou-Akl, T.H., Blowytsky, O., Walters, H.L., Matthew, H.W.T., 2013. Chitosan fibers with improved biological and mechanical properties for tissue engineering applications. J. Mech. Behav. Biomed. Mater. 20, 217-226.
    [5]
    Amiri, H., Aghbashlo, M., Sharma, M., Gaffey, J., Manning, L., Moosavi Basri, S.M., Kennedy, J.F., Gupta, V.K., Tabatabaei, M., 2022. Chitin and chitosan derived from crustacean waste valorization streams can support food systems and the UN Sustainable Development Goals. Nat. Food 3, 822-828.
    [6]
    Arbia, W., Arbia, L., Adour, L., Amrane, A., 2013. Chitin recovery using biological methods. Food Technol. Biotechnol. 51, 12-25.
    [7]
    Arkoun, M., Daigle, F., Heuzey, M.C., Ajji, A., 2017. Antibacterial electrospun chitosan-based nanofibers: a bacterial membrane perforator. Food Sci. Nutr. 5, 865-874.
    [8]
    Arslan, D., Tuccitto, N., Auditore, A., Licciardello, A., Marletta, G., Riolo, M., la Spada, F., Conti Taguali, S., Calpe, J., Meca, G., Pane, A., Cacciola, S.O., Karakeçili, A., 2024. Chitosan-based films grafted with Citrus waste-derived antifungal agents: an innovative and sustainable approach to enhance post-harvest preservation of Citrus fruit. Int. J. Biol. Macromol. 264, 130514.
    [9]
    Astudillo, M.F., Thalwitz, G., Vollrath, F., 2014. Life cycle assessment of Indian silk. J. Clean. Prod. 81, 158-167.
    [10]
    Austero, M.S., Donius, A.E., Wegst, U.G., Schauer, C.L., 2012. New crosslinkers for electrospun chitosan fiber mats. I. Chemical analysis. J. R. Soc. Interface 9, 2551-2562.
    [11]
    Bao, D., Liu, L.S., Sun, T., Han, Y., Meng, F.L., Zhao, M., Yu, Y., Guo, J., Zhang, S., 2020. Solid phase change (SSPC) chitosan-g-mPEG fiber with improved mechanical performance via in-situ wet spinning process. Carbohydr. Polym. 240, 116313.
    [12]
    Barber, P.S., Kelley, S.P., Griggs, C.S., Wallace, S., Rogers, R.D., 2014. Surface modification of ionic liquid-spun chitin fibers for the extraction of uranium from seawater: seeking the strength of chitin and the chemical functionality of chitosan. Green Chem. 16, 1828-1836.
    [13]
    Battampara, P., Nimisha Sathish, T., Reddy, R., Guna, V., Nagananda, G.S., Reddy, N., Ramesha, B.S., Maharaddi, V.H., Rao, A.P., Ravikumar, H.N., Biradar, A., Radhakrishna, P.G., 2020. Properties of chitin and chitosan extracted from silkworm pupae and egg shells. Int. J. Biol. Macromol. 161, 1296-1304.
    [14]
    Bentley, F.E., Passieux, R., David, L., Osorio-Madrazo, A., 2022. Pure chitosan biomedical textile fibers from mixtures of low- and high-molecular weight bidisperse polymer solutions: processing and understanding of microstructure-mechanical properties’ relationship. Int. J. Mol. Sci. 23, 4767.
    [15]
    Boamah, P.O., Onumah, J., Agolisi, M.H., Idan, F., 2023. Application of low molecular weight chitosan in animal nutrition, husbandry, and health: a review. Carbohydr. Polym. Technol. Appl. 6, 100329.
    [16]
    Broeren, M.L.M., Dellaert, S.N.C., Cok, B., Patel, M.K., Worrell, E., Shen, L., 2017. Life cycle assessment of sisal fiber: exploring how local practices can influence environmental performance. J. Clean. Prod. 149, 818-827.
    [17]
    Cai, Y., Cao, J.F., Xu, C., Zhou, J.P., 2019. Thermo-responsive behaviors and bioactivities of hydroxybutyl chitosans prepared in alkali/urea aqueous solutions. Carbohydr. Polym. 215, 90-98.
    [18]
    Cai, Y.P., Mitrano, D.M., Hufenus, R., Nowack, B., 2021. Formation of fiber fragments during abrasion of polyester textiles. Environ. Sci. Technol. 55, 8001-8009.
    [19]
    Carrera, C., Bengoechea, C., Carrillo, F., Calero, N., 2023. Effect of deacetylation degree and molecular weight on surface properties of chitosan obtained from biowastes. Food Hydrocoll. 137, 108383.
    [20]
    Cerqueira, G.R.C., Gomes, D.S., Victor, R.S., Figueiredo, L.R.F., Medeiros, E.S., Neves, G.A., Menezes, R.R., Silva, S.M.L., 2024. Development of PVA/chitosan nanofibers by a green route using solution blow spinning. J. Polym. Environ. 32, 1489-1499.
    [21]
    Chaves, D.M., Araújo, J.C., Gomes, C.V., Gonçalves, S.P., Fangueiro, R., Ferreira, D.P., 2024. Extraction, characterization and properties evaluation of pineapple leaf fibers from Azores pineapple. Heliyon 10, e26698.
    [22]
    Chen, Y., Zhang, Q., Zhong, Y., Wei, P., Yu, X., Huang, J., Cai, J., 2021. Super-strong and super-stiff chitosan filaments with highly ordered hierarchical structure. Adv. Func. Mater. 38, 2104368.
    [23]
    Chen, C.C., Wu, Q.J., Zao, Y.M., Ma, J.R., Wan, Z.M., Li, S.Y., Li, D.G., Jin, Y.C., 2022a. Mechanically strong all-chitin filaments: wet-spinning of β-chitin nanofibers in aqueous NaOH. Int. J. Biol. Macromol. 222, 3243-3249.
    [24]
    Chen, W., Cao, P., Liu, Y.S., Yu, A.L., Wang, D., Chen, L., Sundarraj, R., Yuchi, Z.G., Gong, Y., Merzendorfer, H., Yang, Q., 2022b. Structural basis for directional chitin biosynthesis. Nature 610, 402-408.[PubMed].
    [25]
    Chen, C., Jia, X.Y., Li, X.R., Shi, M.Y., Hu, J.Y., Song, M.Y., Wu, S.W., Dai, H.L., Wang, X.G., Geng, H.Y., 2023. Scalable wet-spinning of wearable chitosan-silica textile for all-day radiative cooling. Chem. Eng. J. 475, 146307.
    [26]
    Cheung, H.Y., Ho, M.P., Lau, K.T., Cardona, F., Hui, D., 2009. Natural fibre-reinforced composites for bioengineering and environmental engineering applications. Compos. Part B Eng. 40, 655-663.
    [27]
    Costa, S.M., Mazzola, P.G., Silva, J.C.A.R., Pahl, R., Pessoa, A. Jr, Costa, S.A., 2013. Use of sugar cane straw as a source of cellulose for textile fiber production. Ind. Crops Prod. 42, 189-194.
    [28]
    Crini, G., 2019. Historical review on chitin and chitosan biopolymers. Environ. Chem. Lett. 17, 1623-1643.
    [29]
    Dai, J.Y., Luo, Y.X., Wu, D.P., Bian, X.E., Xu, J.M., 2025. Carbon footprint analysis for the silk reeling process of raw silk in China: influence of energy type and geographical position on sustainability production. J. Clean. Prod. 528, 146748.
    [30]
    daSilva, H.N., da Silva Barbosa, M.C., de Souza, M.F., de Sousa Lima, A.M., de Almeida Duarte, R.R., Navarro, R.F., de Lima Silva, S.M., Fook, M.V.L., 2025. How molar mass, acid type, and coagulation bath composition influence coagulation kinetics, mechanical properties, and swelling behavior of chitosan filaments: a full factorial approach. Polymers 17, 927.
    [31]
    Deng, J.J., Mao, H.H., Fang, W., Li, Z.Q., Shi, D., Li, Z.W., Zhou, T., Luo, X.C., 2020. Enzymatic conversion and recovery of protein, chitin, and astaxanthin from shrimp shell waste. J. Clean. Prod. 271, 122655.
    [32]
    Ding, C.K., Su, J.L., Yang, N., Luo, Y., Yue, C.F., Wang, H., Xue, M., 2023. Enhanced properties of collagen/chitosan biocomposite fibers by dry-jet wet spinning with a high-aspect-ratio spinneret. J. Polym. Res. 31, 12.
    [33]
    Dissanayake, N.P.J., Summerscales, J., Grove, S.M., Singh, M.M., 2009. Energy use in the production of flax fiber for the reinforcement of composites. J. Nat. Fibres 6, 331-346.
    [34]
    Dong, Q.Q., Qiu, W.Q., Feng, Y.H., Jin, Y.S., Deng, S.G., Tao, N.P., Jin, Y.Z., 2023. Proteases and microwave treatment on the quality of chitin and chitosan produced from white shrimp (Penaeus vannamei). eFood 4, e73.
    [35]
    Draczynski, Z., 2008. Honeybee corpses as an available source of chitin. J. Appl. Polym. Sci. 109, 1974-1981.
    [36]
    Dresvyanina, E.N., Dobrovol’skaya, I.P., Popryadukhin, P.V., Yudin, V.E., Ivan’kova, E.M., Elokhovskii, V.Y., Khomenko, A.Y., 2013. Influence of spinning conditions on properties of chitosan fibers. Fiber Chem. 44, 280-283.
    [37]
    East, G.C., Qin, Y.M., 1993. Wet spinning of chitosan and the acetylation of chitosan fibers. J. Appl. Polym. Sci. 50, 1773-1779.
    [38]
    Edo, G.I., Yousif, E., Al-Mashhadani, M.H., 2024. Chitosan: an overview of biological activities, derivatives, properties, and current advancements in biomedical applications. Carbohydr. Res. 542, 109199.
    [39]
    El-Tahlawy, K., Hudson, S.M., Hebeish, A.A., 2007. Spinnability of chitosan butyrate/cellulose acetate for obtaining a blend fiber. J. Appl. Polym. Sci. 105, 2801-2805.
    [40]
    Erickson, A.E., Edmondson, D., Chang, F.C., Wood, D., Gong, A., Levengood, S.L., Zhang, M.Q., 2015. High-throughput and high-yield fabrication of uniaxially-aligned chitosan-based nanofibers by centrifugal electrospinning. Carbohydr. Polym. 134, 467-474.
    [41]
    Fazeli, M., Islam, S., Baniasadi, H., Abidnejad, R., Schlapp-Hackl, I., Hummel, M., Lipponen, J., 2024. Exploring the potential of regenerated Ioncell fiber composites: a sustainable alternative for high-strength applications. Green Chem. 26, 6822-6835.
    [42]
    Feng, Y.N., Ji, B.Y., Feng, X.L., Rong, L.D., Zhong, Y., Xu, H., Mao, Z.P., Liang, J., Wang, B.J., 2025. Phosphoric acid-based dry-wet spinning of high-performance chitin fibers: chitosan added for enhanced processability and multifunctionality. ACS Appl. Polym. Mater. 7, 9849-9860.
    [43]
    Filho, W.L., Perry, P., Heim, H., Dinis, M.A.P., Moda, H., Ebhuoma, E., Paço, A., 2022. An overview of the contribution of the textiles sector to climate change. Front. Environ. Sci. 10, 973102.
    [44]
    Frazier, R.M., Vivas, K.A., Azuaje, I., Vera, R., Pifano, A., Forfora, N., Jameel, H., Ford, E., Pawlak, J.J., Venditti, R., Gonzalez, R., 2024. Beyond cotton and polyester: an evaluation of emerging feedstocks and conversion methods for the future of fashion industry. J. Bioresour. Bioprod. 9, 130-159.
    [45]
    Fujiwara, E., Cabral, T.D., Sato, M., Oku, H., Cordeiro, C.M.B., 2020. Agarose-based structured optical fibre. Sci. Rep. 10, 7035.
    [46]
    Furer, L.A., Abad, Á.D., Manser, P., Hannig, Y., Schuerle, S., Fortunato, G., Buerki-Thurnherr, T., 2022. Novel electrospun chitosan/PEO membranes for more predictive nanoparticle transport studies at biological barriers. Nanoscale 14, 12136-12152.
    [47]
    Gafri, H.F.S., Zuki, F.M., Aroua, M.K., Hashim, N., 2018. Mechanism of bacterial adhesion on ultrafiltration membrane modified by natural antimicrobial polymers (chitosan) and combination with activated carbon (PAC). Rev. Chem. Eng. 35, 421-443.
    [48]
    Galeda, G., Diaz, E., Goycoolea, F.M., Heras, A., 2008. Influence of N-deacetylation conditions on chitosan production from α-chitin. Nat. Prod. Commun. 3, 1934578X0800300414.
    [49]
    Gan, S., Zakaria, S., Syed Jaafar, S.N., 2017. Enhanced mechanical properties of hydrothermal carbamated cellulose nanocomposite film reinforced with graphene oxide. Carbohydr. Polym. 172, 284-293.
    [50]
    Ge, H.C., Luo, D.K., 2005. Preparation of carboxymethyl chitosan in aqueous solution under microwave irradiation. Carbohydr. Res. 340, 1351-1356.
    [51]
    Geyer, R., Jambeck, J.R., Law, K.L., 2017. Production, use, and fate of all plastics ever made. Sci. Adv. 3, e1700782.
    [52]
    Gomez-Campos, A., Vialle, C., Rouilly, A., Sablayrolles, C., Hamelin, L., 2021. Flax fiber for technical textile: a life cycle inventory. J. Clean. Prod. 281, 125177.
    [53]
    Hérnandez Vázquez, C.I., Draczyński, Z., Borkowski, D., Kaźmierczak, D., 2024. Enhancing chitosan fibers: a dual approach with tripolyphosphate and ursolic acid. Polymers 16, 461.
    [54]
    Hahn, T., Tafi, E., Paul, A., Salvia, R., Falabella, P., Zibek, S., 2020. Current state of chitin purification and chitosan production from insects. J. Chem. Technol. Biotechnol. 95, 2775-2795.
    [55]
    Hassan, M.M., Carr, C.M., 2018. A critical review on recent advancements of the removal of reactive dyes from dyehouse effluent by ion-exchange adsorbents. Chemosphere 209, 201-219.
    [56]
    Hassan, M.M., Hudson, S., 2026. Revolutionizing textile manufacturing: recent advances in the synthesis of chitin derivatives and their application in sustainable processing and multifunctionalization of textiles. Chem. Eng. J. 530, 173420.
    [57]
    Hassan, M.M., 2015. Binding of a quaternary ammonium polymer-grafted-chitosan onto a chemically modified wool fabric surface: assessment of mechanical, antibacterial and antifungal properties. RSC Adv. 5, 35497-35505.
    [58]
    Hassan, M.M., 2018. Enhanced antimicrobial activity and reduced water absorption of chitosan films graft copolymerized with poly(acryloyloxy)ethyltrimethylammonium chloride. Int. J. Biol. Macromol. 118, 1685-1695.
    [59]
    Hassan, M.M., 2025. A comprehensive review of the advances in process engineering and greener solvents in dyeing to impart sustainable textile manufacturing. Sustain. Mater. Technol. 45, e01490.
    [60]
    Hirano, S., Yoshida, S., Takabuchi, N. 1993. N-[13C=O] acetylchitosan and its digestibility by silkworms. Carbohydr. Polym. 22, 137-140.
    [61]
    Hirano, S., Zhang, M., Chung, B.G., Kim, S.K., 2000. The N-acylation of chitosan fibre and the N-deacetylation of chitin fibre and chitin-cellulose blended fibre at a solid state. Carbohydr. Polym. 41, 175-179.
    [62]
    Hirano, S., 2001. Wet-spinning and applications of functional fibers based on chitin and chitosan. Macromol. Symp. 168, 21-30.
    [63]
    Hongkulsup, C., Khutoryanskiy, V.V., Niranjan, K., 2016. Enzyme assisted extraction of chitin from shrimp shells (Litopenaeus vannamei). J. Chem. Technol. Biotechnol. 91, 1250-1256.
    [64]
    Huang, Y.C., Li, R.Y., Chen, J.Y., Chen, J.K., 2016. Biphasic release of gentamicin from chitosan/fucoidan nanoparticles for pulmonary delivery. Carbohydr. Polym. 138, 114-122.
    [65]
    Huang, J.C., Zhong, Y., Zhang, X., Xu, H., Zhu, C.Z., Cai, J., 2021. Continuous pilot-scale wet-spinning of biocompatible chitin/chitosan multifilaments from an aqueous KOH/urea solution. Macromol. Rapid Commun. 42, e2100252.
    [66]
    Ignatova, M., Manolova, N., Rashkov, I., 2007. Novel antibacterial fibers of quaternized chitosan and poly(vinyl pyrrolidone) prepared by electrospinning. Eur. Polym. J. 43, 1112-1122.
    [67]
    Jayakumar, R., Nagahama, H., Furuike, T., Tamura, H., 2008. Synthesis of phosphorylated chitosan by novel method and its characterization. Int. J. Biol. Macromol. 42, 335-339.
    [68]
    Judawisastra, H., Hadyiswanto, I.O.C., Sitohang, R.D.R., Winiati, W., 2015. Improvements of tensile properties and durability of chitosan fiber using methanol drying treatment. Macromol. Symp. 353, 147-153.
    [69]
    Kahigi, N.S., Mkunda, J.J., Mwema, M.F., Machunda, R., 2025. A comprehensive life cycle assessment of sisal yarn production: unveiling sustainability and resource optimization hotspots. Environ. Chall. 18, 101085.
    [70]
    Kalita, N.K., Nagar, M.K., Mudenur, C., Kalamdhad, A., Katiyar, V., 2019. Biodegradation of modified poly(lactic acid) based biocomposite films under thermophilic composting conditions. Polym. Test. 76, 522-536.
    [71]
    Kalliola, S., Repo, E., Srivastava, V., Zhao, F.P., Heiskanen, J.P., Sirviö, J.A., Liimatainen, H., Sillanpää, M., 2018. Carboxymethyl chitosan and its hydrophobically modified derivative as pH-switchable emulsifiers. Langmuir 34, 2800-2806.
    [72]
    Kartik, R., Muthusamy, S., Shelly, K., Surendiran, M., 2025. Chemical modifications of chitin and chitosan fibers and filaments: a review. Macromol. Chem. Phys. 226, 2400422.
    [73]
    Khalili, R., Ghaedi, M., Parvinnia, M., Sabzehmeidani, M.M., 2021. Simultaneous removal of binary mixture dyes using Mn - Fe layered double hydroxide coated chitosan fibers prepared by wet spinning. Surf. Interfaces 23, 100976.
    [74]
    Knaul, J.Z., Hudson, S.M., Creber, K.A.M., 1999a. Improved mechanical properties of chitosan fibers. J. Appl. Polym. Sci. 72, 1721-1732.
    [75]
    Knaul, J.Z., Hudson, S.M., Creber, K.A.M., 1999b. Crosslinking of chitosan fibers with dialdehydes: proposal of a new reaction mechanism. J. Polym. Sci. B Polym. Phys. 37, 1079-1094.
    [76]
    Koumentakou, I., Meretoudi, A., Emmanouil, C., Kyzas, G.Z., 2025. Environmental toxicity and biodegradation of chitosan derivatives: a comprehensive review. J. Ind. Eng. Chem. 146, 70-86.
    [77]
    Kuznik, I., Kruppke, I., Cherif, C., 2022. Pure chitosan-based fibers manufactured by a wet spinning lab-scale process using ionic liquids. Polymers 14, 477.
    [78]
    Lagarto, A., Merino, N., Valdes, O., Dominguez, J., Spencer, E., de la Paz, N., Aparicio, G., 2015. Safety evaluation of chitosan and chitosan acid salts from Panurilus argus lobster. Int. J. Biol. Macromol. 72, 1343-1350.
    [79]
    Lavertu, M., Darras, V., Buschmann, M.D., 2012. Kinetics and efficiency of chitosan reacetylation. Carbohydr. Polym. 87, 1192-1198.
    [80]
    Lee, K.Y., Shibutani, M., Takagi, H., Arimura, T., Takigami, S., Uneyama, C., Kato, N., Hirose, M., 2004a. Subchronic toxicity study of dietary N-acetylglucosamine in F344 rats. Food Chem. Toxicol. 42, 687-695.
    [81]
    Lee, S.H., Park, S.Y., Choi, J.H., 2004b. Fiber formation and physical properties of chitosan fiber crosslinked by epichlorohydrin in a wet spinning system: the effect of the concentration of the crosslinking agent epichlorohydrin. J. Appl. Polym. Sci. 92, 2054-2062.
    [82]
    Lee, S.H., Park, S.M., Kim, Y., 2007. Effect of the concentration of sodium acetate (SA) on crosslinking of chitosan fiber by epichlorohydrin (ECH) in a wet spinning system. Carbohydr. Polym. 70, 53-60.
    [83]
    Lee, H., Kim, J., Myung, S., Jung, T.G., Han, D.W., Kim, B., Lee, J.C., 2024. Extraction of γ-chitosan from insects and fabrication of PVA/γ-chitosan/Kaolin nanofiber wound dressings with hemostatic properties. Discover Nano 19, 77.
    [84]
    Lee, S.H., 2003. Ripening time and fiber formation of chitosan spinning dope. J. Appl. Polym. Sci. 90, 2870-2877.
    [85]
    Li, X.Q., Tang, R.C., 2016a. Crosslinked and dyed chitosan fiber presenting enhanced acid resistance and bioactivities. Polymers 8, 119.
    [86]
    Li, X.Q., Tang, R.C., 2016b. Crosslinking of chitosan fiber by a water-soluble diepoxy crosslinker for enhanced acid resistance and its impact on fiber structures and properties. React. Funct. Polym. 100, 116-122.
    [87]
    Li, J.H., Zhuang, S.L., 2020. Antibacterial activity of chitosan and its derivatives and their interaction mechanism with bacteria: current state and perspectives. Eur. Polym. J. 138, 109984.
    [88]
    Li, L., Yuan, B., Liu, S.W., Yu, S.T., Xie, C.X., Liu, F.S., Guo, X.Y., Pei, L.J., Zhang, B.Q., 2012a. Preparation of high strength chitosan fibers by using ionic liquid as spinning solution. J. Mater. Chem. 22, 8585.
    [89]
    Li, Y.L., Zhuang, P.Y., Zhang, Y.F., Wang, Z.K., Hu, Q.L., 2012b. A new approach for preparing chitosan fibers from a LiOH/urea solvent system. Mater. Lett. 84, 73-76.
    [90]
    Li, B., Shi, Y., Shan, C.L., Zhou, Q., Ibrahim, M., Wang, Y.L., Wu, G.X., Li, H.Y., Xie, G.L., Sun, G.C., 2013. Effect of chitosan solution on the inhibition of Acidovorax citrulli causing bacterial fruit blotch of watermelon. J. Sci. Food Agric. 93, 1010-1015.
    [91]
    Li, Y.H., Sun, J.K., Du, Q.J., Zhang, L.H., Yang, X.X., Wu, S.L., Xia, Y.Z., Wang, Z.H., Xia, L.H., Cao, A.Y., 2014. Mechanical and dye adsorption properties of graphene oxide/chitosan composite fibers prepared by wet spinning. Carbohydr. Polym. 102, 755-761.
    [92]
    Li, J.H., Fu, J.M., Tian, X., Hua, T., Poon, T., Koo, M., Chan, W., 2022. Characteristics of chitosan fiber and their effects towards improvement of antibacterial activity. Carbohydr. Polym. 280, 119031.
    [93]
    Li, X., Li, X., Sun, L.R., Zhang, Y., Li, Q.Z., Zhu, L.S., Wang, L.L., 2024. Discussion on key issues of carbon footprint accounting for wool products. J. Clean. Prod. 445, 141336.
    [94]
    Lindh, A., Wijayarathna, E.R.K.B., Ciftci, G.C., Syed, S., Bashir, T., Kadi, N., Zamani, A., 2024. Dry gel spinning of fungal hydrogels for the development of renewable yarns from food waste. Fungal Biol. Biotechnol. 11, 9.
    [95]
    Liu, L., Yang, H., Lou, Y., Wu, J.Y., Miao, J., Lu, X.Y., Gao, J.Q., 2019. Enhancement of oral bioavailability of salmon calcitonin through chitosan-modified, dual drug-loaded nanoparticles. Int. J. Pharm. 557, 170-177.
    [96]
    Lyshtva, P., Voronova, V., Barbir, J., Leal Filho, W., Kröger, S.D., Witt, G., Miksch, L., Sabowski, R., Gutow, L., Frank, C., Emmerstorfer-Augustin, A., Agustin-Salazar, S., Cerruti, P., Santagata, G., Stagnaro, P., D’Arrigo, C., Vignolo, M., Krång, A.S., Strömberg, E., Lehtinen, L., Annunen, V., 2024. Degradation of a poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) compound in different environments. Heliyon 10, e24770.
    [97]
    Másson, M., 2024. The quantitative molecular weight-antimicrobial activity relationship for chitosan polymers, oligomers, and derivatives. Carbohydr. Polym. 337, 122159.
    [98]
    Ma, B.M., Qin, A.W., Li, X., He, C.J., 2013. High tenacity regenerated chitosan fibers prepared by using the binary ionic liquid solvent (Gly·HCl)-[Bmim]Cl. Carbohydr. Polym. 97, 300-305.
    [99]
    Ma, J.H., Xin, C., Tan, C.J., 2015a. Preparation, physicochemical and pharmaceutical characterization of chitosan from Catharsius molossus residue. Int. J. Biol. Macromol. 80, 547-556.
    [100]
    Ma, B.M., Hou, X.L., He, C.J., 2015b. Preparation of chitosan fibers using aqueous ionic liquid as the solvent. Fibres. Polym. 16, 2704-2708.
    [101]
    Marin, L., Andreica, B.I., Ailincai, D., Anisiei, A., Lungu, R., 2025. Chitosan: a critical review of structural characteristics-properties relationship. Cellulose Chem. Technol. 59, 747-759.
    [102]
    Marquez-Bravo, S., Doench, I., Molina, P., Bentley, F.E., Tamo, A.K., Passieux, R., Lossada, F., David, L., Osorio-Madrazo, A., 2021. Functional bionanocomposite fibers of chitosan filled with cellulose nanofibers obtained by gel spinning. Polymers 13, 1563.
    [103]
    Masood, R., Hussain, T., Miraftab, M., Ullah, A., Ali Raza, Z., Areeb, T., Umar, M., 2017. Novel alginate, chitosan, and Psyllium composite fiber for wound-care applications. J. Ind. Text. 47, 20-37.
    [104]
    Mohammadkhani, G., Kumar Ramamoorthy, S., Adolfsson, K.H., Mahboubi, A., Hakkarainen, M., Zamani, A., 2021. New solvent and coagulating agent for development of chitosan fibers by wet spinning. Polymers 13, 2121.
    [105]
    Moriam, K., Sawada, D., Nieminen, K., Hummel, M., Ma, Y.B., Rissanen, M., Sixta, H., 2021. Towards regenerated cellulose fibers with high toughness. Cellulose 28, 9547-9566.
    [106]
    Muñoz, I., Rodríguez, C., Gillet, D., M Moerschbacher, B., 2018. Life cycle assessment of chitosan production in India and Europe. Int. J. Life Cycle Assess. 23, 1151-1160.
    [107]
    Mundsinger, K., Müller, A., Beyer, R., Hermanutz, F., Buchmeiser, M.R., 2015. Multifilament cellulose/chitin blend yarn spun from ionic liquids. Carbohydr. Polym. 131, 34-40.
    [108]
    Murata, H., Koepsel, R.R., Matyjaszewski, K., Russell, A.J., 2007. Permanent, non-leaching antibacterial surfaces: 2: how high density cationic surfaces kill bacterial cells. Biomaterials 28, 4870-4879.
    [109]
    Nechyporchuk, O., Yang Nilsson, T., Ulmefors, H., Köhnke, T., 2020. Wet spinning of chitosan fibers: effect of sodium dodecyl sulfate adsorption and enhanced dope temperature. ACS Appl. Polym. Mater. 2, 3867-3875.
    [110]
    Nguyen, K.D., 2021. Temperature effect of water coagulation bath on chitin fiber prepared through wet-spinning process. Polymers 13, 1909.
    [111]
    Niinimäki, K., Peters, G., Dahlbo, H., Perry, P., Rissanen, T., Gwilt, A., 2020. The environmental price of fast fashion. Nat. Rev. Earth Environ. 1, 189-200.
    [112]
    Notin, L., Viton, C., David, L., Alcouffe, P., Rochas, C., Domard, A., 2006. Morphology and mechanical properties of chitosan fibers obtained by gel-spinning: influence of the dry-jet-stretching step and ageing. Acta Biomater. 2, 387-402.
    [113]
    Oberlintner, A., Bajić, M., Kalčíková, G., Likozar, B., Novak, U., 2021. Biodegradability study of active chitosan biopolymer films enriched with Quercus polyphenol extract in different soil types. Environ. Technol. Innov. 21, 101318.
    [114]
    Ota, A., Beyer, R., Hageroth, U., Müller, A., Tomasic, P., Hermanutz, F., Buchmeiser, M.R., 2021. Chitin/cellulose blend fibers prepared by wet and dry-wet spinning. Polym. Adv. Technol. 32, 335-342.
    [115]
    Pantaleone, D., Yalpani, M., Scollar, M., 1992. Unusual susceptibility of chitosan to enzymic hydrolysis. Carbohydr. Res. 237, 325-332.
    [116]
    Paula, H.C.B., Silva, R.B.C., Santos, C.M., Dantas, F.D.S., de Paula, R.C.M., de Lima, L.R.M., de Oliveira, E.F., Figueiredo, E.A.T., Dias, F.G.B., 2020. Eco-friendly synthesis of an alkyl chitosan derivative. Int. J. Biol. Macromol. 163, 1591-1598.
    [117]
    Peniche, H., Razonado, I.A., Alcouffe, P., Sudre, G., Peniche, C., Osorio-Madrazo, A., David, L., 2024. Wet-spun chitosan-sodium caseinate fibers for biomedicine: from spinning process to physical properties. Int. J. Mol. Sci. 25, 1768.
    [118]
    Perrin, N., Mohammadkhani, G., Homayouni Moghadam, F., Delattre, C., Zamani, A., 2022. Biocompatible fibers from fungal and shrimp chitosans for suture application. Curr. Res. Biotechnol. 4, 530-536.
    [119]
    Pervez, M.N., Hassan, M.M., Naddeo, V., 2024. Separation of cationic methylene blue dye from its aqueous solution by S-sulfonated wool keratin-based sustainable electrospun nanofibrous membrane biosorbent. Sep. Purif. Technol. 333, 125903.
    [120]
    Pillai, C.K.S., Paul, W., Sharma, C.P., 2009. Chitin and chitosan polymers: chemistry, solubility and fiber formation, Prog. Polym. Sci. 34, 641-678.
    [121]
    Qian, L., Zhang, K., Guo, X., Yu, M., 2023. What happens when chitin becomes chitosan? A single-molecule study. RSC Adv. 13, 2294-2300.
    [122]
    Qian, C., 2011. A new non-woven material and its use in functional baby diapers. Res. J. Text. Appar. 15, 66-71.
    [123]
    Qin, Y. 1990. The Production of Fibers From Chitosan. Leeds: University of Leeds.
    [124]
    Rahayu, A.P., Islami, A.F., Saputra, E., Sulmartiwi, L., Rahmah, A.U., Kurnia, K.A., 2022. The impact of the different types of acid solution on the extraction and adsorption performance of chitin from shrimp shell waste. Int. J. Biol. Macromol. 194, 843-850.
    [125]
    Rathke, T.D., Hudson, S.M., 1994. Review of chitin and chitosan as fiber and film formers. J. Macromol. Sci. Part C 34, 375-437.
    [126]
    Rehman, H.U., Cord-Landwehr, S., Shapaval, V., Dzurendova, S., Kohler, A., Moerschbacher, B.M., Zimmermann, B., 2023. High-throughput vibrational spectroscopy methods for determination of degree of acetylation for chitin and chitosan. Carbohydr. Polym. 302, 120428.
    [127]
    Ruangnarong, C., Khojitmate, S., Srivorradatphisan, S., Panyathikun, N., Chonsakorn, S., 2024. Evaluation of mechanically extracted banana fibers from pseudostem layers: a sustainable textile raw material. Heliyon 10, e39880.
    [128]
    Safari, P., Rahimabadi, E.Z., Vaezi, M.R., Behnamghader, A., Tahergorabi, R., 2025. Development of ZnO-NPs reinforced chitosan nanofiber mats with improved antibacterial and biocompatibility properties. Sci. Rep. 15, 16567.
    [129]
    Schmutz, M., Hischier, R., Som, C., 2021. Factors allowing users to influence the environmental performance of their T-shirt. Sustainability 13, 2498.
    [130]
    Seberi Riseh, R., Vatankhah, M., Hassanisaadi, M., Khandani, Y., Skorik, Y.A., 2026. Chitosan-based biostimulants for improving soil health, water and nutrient availability. Sci. Total Environ. 1013, 181305.
    [131]
    Shao, Z.Z., Vollrath, F., 2002. Surprising strength of silkworm silk. Nature 418, 741.
    [132]
    Shao, K., Han, B.Q., Gao, J.N., Jiang, Z.W., Liu, W.Z., Liu, W.S., Liang, Y., 2016. Fabrication and feasibility study of an absorbable diacetyl chitin surgical suture for wound healing. J. Biomed. Mater. Res. Part B Appl. Biomater. 104, 116-125.
    [133]
    Siafaka, P.I., Titopoulou, A., Koukaras, E.N., Kostoglou, M., Koutris, E., Karavas, E., Bikiaris, D.N., 2015. Chitosan derivatives as effective nanocarriers for ocular release of timolol drug. Int. J. Pharm. 495, 249-264.
    [134]
    Sibaja, B., Culbertson, E., Marshall, P., Boy, R., Broughton, R.M., Solano, A.A., Esquivel, M., Parker, J., de la Fuente, L., Auad, M.L., 2015. Preparation of alginate-chitosan fibers with potential biomedical applications. Carbohydr. Polym. 134, 598-608.
    [135]
    Sieber, V., Hofer, M., Brück, W.M., Garbe, D., Brück, T., Lynch, C.A., 2018. ChiBio: an integrated bio-refinery for processing chitin-rich bio-waste to specialty chemicals. Grand Challenges in Marine Biotechnology. Cham: Springer International Publishing, 555-578.
    [136]
    Singh, A.K., Kumar, M., Mitra, S., 2018. Carbon footprint and energy use in jute and allied fibre production. Indian J. Agric. Sci. 88, 1305-1311.
    [137]
    Staszczyk, K., Mania, S., Tylingo, R., 2026. Sustainable fabrication and structure-property evaluation of chitosan-based functional membranes prepared via a CO2-assisted process. Carbohydr. Polym. 377, 124888.
    [138]
    Svensson, S.E., Ferreira, J.A., Hakkarainen, M., Adolfsson, K.H., Zamani, A., 2021. Fungal textiles: wet spinning of fungal microfibers to produce monofilament yarns. Sustain. Mater. Technol. 28, e00256.
    [139]
    Tachibana, M., Yaita, A., Taniura, H., Fukasawa, K., Nagasue, N., Nakamura, T., 1988. The use of chitin as a new absorbable suture material: an experimental study. Jpn. J. Surg. 18, 533-539.
    [140]
    Tacon, A.G.J., 2018. Global trends in aquaculture and compound aquafeed production. World Aquac. 49, 33-46.
    [141]
    Taheri, P., Khajeh-Amiri, A., 2020. Antibacterial cotton fabrics via immobilizing silver phosphate nanoparticles onto the chitosan nanofiber coating. Int. J. Biol. Macromol. 158, 282-289.
    [142]
    Tezcan, F., Donat, R., Şarkaya, K., 2025. Electrospun chitosan/poly(ethylene oxide) nanofiber hydrogels with tunable glutaraldehyde crosslinking for wound healing. Polym. Bull. 83, 26.
    [143]
    Tien, N.D., Geng, T.X., Heyward, C.A., Reseland, J.E., Lyngstadaas, S.P., Blaker, J.J., Haugen, H.J., 2022. Solution blow spinning of highly deacetylated chitosan nanofiber scaffolds for dermal wound healing. Biomater. Adv. 137, 212871.
    [144]
    Toskas, G., Brünler, R., Hund, H., Hund, R.D., Hild, M., Aibibu, D., Cherif, C., 2013. Pure chitosan microfibers for biomedical applications. Autex Res. J. 13, 134-140.
    [145]
    Tran, T.A., Doench, I., Tamo, A.K., Jahangir, S., Marquez-Bravo, S., Molina, P., Helmstaedter, M., Helguera, A.M., Gorzelanny, C., Osorio-Madrazo, A., 2025. Biopolymer fibers of high strength and enhanced orientation by the synergy of high/low molecular weight chitosans in hybrid biomaterials processed by gel spinning. J. Funct. Biomater. 16, 405.
    [146]
    Vicente, F.A., Hren, R., Novak, U., Čuček, L., Likozar, B., Vujanović, A., 2024. Energy demand distribution and environmental impact assessment of chitosan production from shrimp shells. Renew. Sustain. Energy Rev. 192, 114204.
    [147]
    Wang, J.T., Wu, J.L., Han, F.L., 2019. Eco-friendly and scratch-resistant hybrid coating on mesh for gravity-driven oil/water separation. J. Clean. Prod. 241, 118369.
    [148]
    Wang, L., Ezazi, N.Z., Liu, L., Ajdary, R., Xiang, W.C., Borghei, M., Santos, H.A., Rojas, O.J., 2020. Microfibers synthesized by wet-spinning of chitin nanomaterials: mechanical, structural and cell proliferation properties. RSC Adv. 10, 29450-29459.
    [149]
    Wang, X.K., Shan, C.C., Huang, R.L., Penkova, A., Su, R.X., 2025. Chitosan and chitosan nanofibers in wound dressings, from material preparation to functional design: a review. Int. J. Biol. Macromol. 333, 148937.
    [150]
    Wang, J., Ji, X., Liao, X., Chen, Y., Song, H., Zhang, W., 2025. Comparison of microstructural evolution differences during dry-jet wet spinning and wet spinning for polyacrylonitrile precursor fiber. Sci Rep. 15, 27128.
    [151]
    Wang, Y.W., Lyu, T.M., Wei, C.H., Gong, C.Y., Zeng, Y., He, J., Xie, H.X., Luo, Y., Xia, Z.G., Jia, H., Peng, X., Dong, K., 2026. Closed-loop recyclable and continuously processable chitosan-based self-powered fibers for human motion perception. Chem. Eng. J. 530, 173618.
    [152]
    Watthanaphanit, A., Supaphol, P., Furuike, T., Tokura, S., Tamura, H., Rujiravanit, R., 2009. Novel chitosan-spotted alginate fibers from wet-spinning of alginate solutions containing emulsified chitosan-citrate complex and their characterization. Biomacromolecules 10, 320-327.
    [153]
    Wei, Y.C., Hudson, S.M., Mayer, J.M., Kaplan, D.L., 1992. The crosslinking of chitosan fibers. J. Polym. Sci. A Polym. Chem. 30, 2187-2193.
    [154]
    Wei, C.Y., Yang, X.D., Liu, X.H., Qiao, C.D., Wang, L., Dong, J., Zhai, Y., 2025. A review of hydrophobic modification of chitosan for enhanced transdermal drug delivery and skin repair. React. Funct. Polym. 217, 106468.
    [155]
    Wiedemann, S.G., Yan, M.J., Henry, B.K., Murphy, C.M., 2016. Resource use and greenhouse gas emissions from three wool production regions in Australia. J. Clean. Prod. 122, 121-132.
    [156]
    Wijayarathna, E.R.K.B., Mohammadkhani, G., Moghadam, F.H., Berglund, L., Ferreira, J.A., Adolfsson, K.H., Hakkarainen, M., Zamani, A., 2024. Tunable fungal monofilaments from food waste for textile applications. Glob. Chall. 8, 2300098.
    [157]
    Xie, H.B., Zhang, S.B., Li, S.H., 2006. Chitin and chitosan dissolved in ionic liquids as reversible sorbents of CO2. Green Chem. 8, 630.
    [158]
    Xu, H.Z., Yagi, S., Ashour, S., Du, L., Hoque, M.E., Tan, L., 2023. A review on current nanofiber technologies: electrospinning, centrifugal spinning, and electro-centrifugal spinning. Macromol. Mater. Eng. 308, 2200502.
    [159]
    Yan, W.X., Shen, L.B., Ji, Y.L., Yang, Q., Shen, X.Y., 2014. Chitin nanocrystal reinforced wet-spun chitosan fibers. J. Appl. Polym. Sci. 131, 40852.
    [160]
    Yang, Q., Dou, F.D., Liang, B.R., Shen, Q., 2005. Studies of cross-linking reaction on chitosan fiber with glyoxal. Carbohydr. Polym. 59, 205-210.
    [161]
    Yang, Y.M., Hu, W., Wang, X.D., Gu, X.S., 2007. The controlling biodegradation of chitosan fibers by N-acetylation in vitro and in vivo. J. Mater. Sci. Mater. Med. 18, 2117-2121.
    [162]
    Yang, T., Luo, J.L., Nowack, B., 2021. Characterization of nanoplastics, fibrils, and microplastics released during washing and abrasion of polyester textiles. Environ. Sci. Technol. 55, 15873-15881.
    [163]
    Yang, W.Q., Zhang, Z.H., Liu, K.B., Wang, W.J., Peng, W.T., Ma, H., Wang, Q., Shi, X.N., Sun, H., Duan, X.L., 2023. Electrospun Fe3O4-chitosan/polyvinyl alcohol nanofibrous film for improved capture and elimination of foodborne pathogens. Int. J. Biol. Macromol. 253, 126692.
    [164]
    Yu, Z.H., Yang, Y., 2025. Carbon footprint of global cotton production. Resour. Environ. Sustain. 20, 100214.
    [165]
    Yudin, V.E., Dobrovolskaya, I.P., Neelov, I.M., Dresvyanina, E.N., Popryadukhin, P.V., Ivan’kova, E.M., Elokhovskii, V.Y., Kasatkin, I.A., Okrugin, B.M., Morganti, P., 2014. Wet spinning of fibers made of chitosan and chitin nanofibrils. Carbohydr. Polym. 108, 176-182.
    [166]
    Zang, C., Zhang, Y.J., Yang, W.G., Hu, Y.H., 2024. Polycaprolactone/chitosan electrospun nanofibrous membranes loaded Chinese yam polysaccharide for active food packaging. LWT 198, 115985.
    [167]
    Zhang, C.P., Zhang, Y., Hao, X.Y., Liu, H., Lv, X., Zhu, J.F., Han, W.L., Zhang, Y.H., 2018. Fabrication of reduced graphene oxide/chitosan composite fiber by dry-jet wet spinning. Adv. Compos. Hybrid Mater. 1, 347-355.
    [168]
    Zhang, B.W., Jiang, Z., Li, X., Wu, Z.Y., Liu, Y.M., Hu, J., Zhang, C.H., Chen, J.Y., Zhou, Y.S., Rao, J., Liu, X., 2023. Facile preparation of biocompatible and antibacterial water-soluble films using polyvinyl alcohol/carboxymethyl chitosan blend fibers via centrifugal spinning. Carbohydr. Polym. 317, 121062.
    [169]
    Zhang, J., Hu, D., Yu, X., Liu, M., He, F., Wang, Y., Shi, X., 2026. Well-aligned hierarchical design of high strength anisotropic chitosan fibers by electrostatic regulation for absorbable sutures. Adv. Healthc. Mater. 15, e04530.
    [170]
    Zheng, L.Y., Zhu, J.F., 2003. Study on antimicrobial activity of chitosan with different molecular weights. Carbohydr. Polym. 54, 527-530.
    [171]
    Zhong, Y., Zhuang, C.J., Gu, W.Q., Zhao, Y.Y., 2019. Effect of molecular weight on the properties of chitosan films prepared using electrostatic spraying technique. Carbohydr. Polym. 212, 197-205.
    [172]
    Zhong, Y., Cai, J., Zhang, L.N., 2020. A review of chitin solvents and their dissolution mechanisms. Chin. J. Polym. Sci. 38, 1047-1060.
    [173]
    Zhou, Y.C., Bao, D., Sun, S.N., Cheng, C., Zhang, S., Qing, M.L., Zhao, M., Guo, J., 2023. Chitosan grafting coumarin-3-carboxylic acid fluorescent fiber with enhanced strength prepared by in-situ wet-spinning. Int. J. Biol. Macromol. 228, 638-646.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (16) PDF downloads(2) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return