Synthesis and Application of UV-curable Phosphorous-Containing Acrylated Epoxidized Soybean Oil-based Resins

HU Yun; JIA Puyou; SHANG Qianqian; ZHANG Meng; FENG Guodong; LIU Chengguo; ZHOU Yonghong

doi:10.12162/jbb.v4i3.007

Volume 4 Issue 3

Aug. 2019

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Article Navigation > Journal of Bioresources and Bioproducts > 2019 > 4(3): 183-191

HU Yun, JIA Puyou, SHANG Qianqian, ZHANG Meng, FENG Guodong, LIU Chengguo, ZHOU Yonghong. Synthesis and Application of UV-curable Phosphorous-Containing Acrylated Epoxidized Soybean Oil-based Resins[J]. Journal of Bioresources and Bioproducts, 2019, 4(3): 183-191. doi: 10.12162/jbb.v4i3.007

Citation:

HU Yun, JIA Puyou, SHANG Qianqian, ZHANG Meng, FENG Guodong, LIU Chengguo, ZHOU Yonghong. Synthesis and Application of UV-curable Phosphorous-Containing Acrylated Epoxidized Soybean Oil-based Resins[J]. Journal of Bioresources and Bioproducts, 2019, 4(3): 183-191. doi: 10.12162/jbb.v4i3.007

Citation:

HU Yun, JIA Puyou, SHANG Qianqian, ZHANG Meng, FENG Guodong, LIU Chengguo, ZHOU Yonghong. Synthesis and Application of UV-curable Phosphorous-Containing Acrylated Epoxidized Soybean Oil-based Resins[J]. Journal of Bioresources and Bioproducts, 2019, 4(3): 183-191. doi: 10.12162/jbb.v4i3.007

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Synthesis and Application of UV-curable Phosphorous-Containing Acrylated Epoxidized Soybean Oil-based Resins

doi: 10.12162/jbb.v4i3.007

1.
Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry; Key Lab of Biomass Energy and Material, Jiangsu Province; National Engineering Lab for Biomass Chemical Utilization; Key Lab on Forest Chemical Engineering, State Forestry Administration; Nanjing 210042, China
2.
Co-Innovationof Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China

More Information

Corresponding author: Chengguo LIU, E-mail:liuchengguo@icifp.cn; Yonghong ZHOU, E-mail:zyh@icifp.cn
Received Date: 2019-01-20
Accepted Date: 2019-03-19
Publish Date: 2019-07-01

Abstract

Abstract

A novel phosphorous-containing acrylated epoxidized soybean oil-based (P-AESO) resin was developed via the ring-opening reaction of epoxidized soybean oil (ESO) with diphenylphosphinic chloride (DPPC), followed by acrylation of the resulting groups. The chemical structure was characterized by Fourier transform infrared spectroscopy (FT-IR), and ¹H nuclear magnetic resonance (¹H NMR). Subsequently, the viscosity and volumetric shrinkage of the obtained P-AESO resins were studied. Then the oligomer was formulated into UV-curable coatings, and the mechanical, thermal, and coating properties of the resulting UV-cured bioresins were studied by tensile testing, dynamic mechanical thermal analysis (DMA), thermogravimetric analysis (TGA) coupled with FT-IR spectroscopy (TGA-FT-IR), hardness, adhesion, pencil hardness and chemical resistance. Furthermore, the UV-curing behavior of the P-AESO resin was determined by real-time realtime infrared (RT-IR). Meanwhile, compared with coating from acrylated epoxidized soybean oil (AESO), the P-AESO system coatings showed better volumetric shrinkage, excellent adhesion, and enhanced thermal and glass transition temperature (T_g) while maintaining reasonably final C=C conversions and cross-link density. For instance, the obtained P-AESO/trimethylolpropanetriacrylate (TMPTA) 20 material possessed a volumetric shrinkage of 4.1%, Tg of 115.6℃, char yield of 9.47%, and final C=C conversions of 81.4% respectively, which exhibited superior values than that of the AESO/TMPTA20 material. The improvement of the P-AESO coating performances could contribute to the architectures that combined the structural features of phosphorous-containing rigid benzene. The developed P-AESO resin is promising for applications in the UV-curable coatings.
- biobased,
- UV-curable coatings,
- acrylated epoxidized soybean oil,
- diphenylphosphinic chloride

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References(31)

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