Cellulose microspheres were fabricated on the basis of sol-gel transition using NaOH/urea/H
2O as the solvent system. These microspheres had an average diameter of about 30 μm. Upon modification with Fe
3O
4 and poly (DOPAm-
co-PFOEA), superhydrophobic magnetic cellulose microspheres were generated, which were analyzed by FTIR, TG, XRD, XPS and water contact angle tests. Magnetic cellulose microspheres contained approximately 15 wt% of Fe
3O
4. Poly(DOPAm-
co-PFOEA)/Fe
3O
4/cellulose microspheres and had a low surface energy and a high water-repellency. These superhydrophobic microspheres were also converted into liquid marbles via an easily scalable process.